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Huang, Xiao
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Sjödin, M., Emanuelsson, R., Sterby, M., Huang, H., Huang, X., Gogoll, A. & Strömme, M. (2018). Quinone-Substituted Conducting Polymers as Electrode Materials for All-Organic Proton Batteries. In: : . Paper presented at 69th Annual Meeting of the International Society of Electrochemistry, 2 - 7 September 2018 Bologna, Italy. Uppsala
Öppna denna publikation i ny flik eller fönster >>Quinone-Substituted Conducting Polymers as Electrode Materials for All-Organic Proton Batteries
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2018 (Engelska)Konferensbidrag, Muntlig presentation med publicerat abstract (Refereegranskat)
Ort, förlag, år, upplaga, sidor
Uppsala: , 2018
Nationell ämneskategori
Nanoteknik
Forskningsämne
Teknisk fysik med inriktning mot nanoteknologi och funktionella material
Identifikatorer
urn:nbn:se:uu:diva-365692 (URN)
Konferens
69th Annual Meeting of the International Society of Electrochemistry, 2 - 7 September 2018 Bologna, Italy
Tillgänglig från: 2018-11-12 Skapad: 2018-11-12 Senast uppdaterad: 2019-03-13Bibliografiskt granskad
Sterby, M., Emanuelsson, R., Huang, X., Gogoll, A., Strömme, M. & Sjödin, M. (2017). Characterization of PEDOT-Quinone Conducting Redox Polymers for Water Based Secondary Batteries. Electrochimica Acta, 235, 356-364
Öppna denna publikation i ny flik eller fönster >>Characterization of PEDOT-Quinone Conducting Redox Polymers for Water Based Secondary Batteries
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2017 (Engelska)Ingår i: Electrochimica Acta, ISSN 0013-4686, E-ISSN 1873-3859, Vol. 235, s. 356-364Artikel i tidskrift (Refereegranskat) Published
Abstract [en]

Lithium-ion technologies show great promise to meet the demands that the transition towards renewable energy sources and the electrification of the transport sector put forward. However, concerns regarding lithium-ion batteries, including limited material resources, high energy consumption during production, and flammable electrolytes, necessitate research on alternative technologies for electrochemical energy storage. Organic materials derived from abundant building blocks and with tunable properties, together with water based electrolytes, could provide safe, inexpensive and sustainable alternatives. In this study, two conducting redox polymers based on poly(3,4-ethylenedioxythiophene) (PEDOT) and a hydroquinone pendant group have been synthesized and characterized in an acidic aqueous electrolyte. The polymers were characterized with regards to kinetics, pH dependence, and mass changes during oxidation and reduction, as well as their conductance. Both polymers show redox matching, i.e. the quinone redox reaction occurs within the potential region where the polymer is conducting, and fast redox conversion that involves proton cycling during pendant group redox conversion. These properties make the presented materials promising candidates as electrode materials for water based all-organic batteries.

Nyckelord
Conducting Redox Polymer, Quinone, Organic Batteries, Proton Batteries, Redox Matching
Nationell ämneskategori
Nanoteknik
Forskningsämne
Teknisk fysik med inriktning mot nanoteknologi och funktionella material
Identifikatorer
urn:nbn:se:uu:diva-319049 (URN)10.1016/j.electacta.2017.03.068 (DOI)000398330200042 ()
Forskningsfinansiär
Stiftelsen för strategisk forskning (SSF)VetenskapsrådetCarl Tryggers stiftelse för vetenskaplig forskning EnergimyndighetenEU, Horisont 2020, 644631
Tillgänglig från: 2017-03-30 Skapad: 2017-03-30 Senast uppdaterad: 2019-05-09Bibliografiskt granskad
Sjödin, M., Emanuelsson, R., Sterby, M., Strietzel, C., Yang, L., Huang, H., . . . Strömme, M. (2017). Conducting Redox Polymer Based Batteries. In: : . Paper presented at Organic Battery Days, Uppsala, June 8-9, 2017..
Öppna denna publikation i ny flik eller fönster >>Conducting Redox Polymer Based Batteries
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2017 (Engelska)Konferensbidrag, Muntlig presentation med publicerat abstract (Refereegranskat)
Nationell ämneskategori
Nanoteknik
Forskningsämne
Teknisk fysik med inriktning mot nanoteknologi och funktionella material
Identifikatorer
urn:nbn:se:uu:diva-334410 (URN)
Konferens
Organic Battery Days, Uppsala, June 8-9, 2017.
Tillgänglig från: 2017-11-23 Skapad: 2017-11-23 Senast uppdaterad: 2017-12-13Bibliografiskt granskad
Huang, X. (2017). Conducting Redox Polymers for Electrode Materials: Synthetic Strategies and Electrochemical Properties. (Doctoral dissertation). Uppsala: Acta Universitatis Upsaliensis
Öppna denna publikation i ny flik eller fönster >>Conducting Redox Polymers for Electrode Materials: Synthetic Strategies and Electrochemical Properties
2017 (Engelska)Doktorsavhandling, sammanläggning (Övrigt vetenskapligt)
Abstract [en]

Organic electrode materials represent an intriguing alternative to their inorganic counterparts due to their sustainable and environmental-friendly properties. Their plastic character allows for the realization of light-weight, versatile and disposable devices for energy storage. Conducting redox polymers (CRPs) are one type of the organic electrode materials involved, which consist of a π-conjugated polymer backbone and covalently attached redox units, the so-called pendant. The polymer backbone can provide conductivity while it is oxidized or reduced (i. e., p- or n-doped) and the concurrent redox chemistry of the pendant provides charge capacity. The combination of these two components enables CRPs to provide both high charge capacity and high power capability. This dyad polymeric framework provides a solution to the two main problems associated with organic electrode materials based on small molecules: the dissolution of the active material in the electrolyte, and the sluggish charge transport within the material. This thesis introduces a general synthetic strategy to obtain the monomeric CRPs building blocks, followed by electrochemical polymerization to afford the active CRPs material. The choice of pendant and of polymer backbone depends on the potential match between these two components, i.e. the redox reaction of the pendant and the doping of backbone occurring within the same potential region. In the thesis, terephthalate and polythiophene were selected as the pendant and polymer backbone respectively, to get access to low potential CRPs. It was found that the presence of a non-conjugated linker between polymer backbone and pendant is essential for the polymerizability of the monomers as well as for the preservation of individual redox activities. The resulting CRPs exhibited fast charge transport within the polymer film and low activation barriers for charge propagation. These low potential CRPs were designed as the anode materials for energy storage applications. The combination of redox active pendant as charge carrier and a conductive polymer backbone reveals new insights into the requirements of organic matter based electrical energy storage materials.

Ort, förlag, år, upplaga, sidor
Uppsala: Acta Universitatis Upsaliensis, 2017. s. 83
Serie
Digital Comprehensive Summaries of Uppsala Dissertations from the Faculty of Science and Technology, ISSN 1651-6214 ; 1604
Nyckelord
Organic electrode material, Energy storage, Conducting redox polymer, Polythiophene, Terephthalate, PEDOT
Nationell ämneskategori
Nanoteknik Organisk kemi Fysikalisk kemi Polymerkemi
Forskningsämne
Kemi med inriktning mot organisk kemi
Identifikatorer
urn:nbn:se:uu:diva-334562 (URN)978-91-513-0168-6 (ISBN)
Disputation
2018-01-19, B41, BMC, Husargatan, Uppsala, 09:15 (Engelska)
Opponent
Handledare
Forskningsfinansiär
SweGRIDS - Swedish Centre for Smart Grids and Energy StorageVetenskapsrådetStiftelsen för strategisk forskning (SSF)
Tillgänglig från: 2017-12-21 Skapad: 2017-11-23 Senast uppdaterad: 2018-03-08
Yang, L., Huang, X., Mamedov, F., Zhang, P., Gogoll, A., Strömme, M. & Sjödin, M. (2017). Conducting redox polymers with non-activated charge transport properties. Physical Chemistry, Chemical Physics - PCCP, 19(36), 25052-25058
Öppna denna publikation i ny flik eller fönster >>Conducting redox polymers with non-activated charge transport properties
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2017 (Engelska)Ingår i: Physical Chemistry, Chemical Physics - PCCP, ISSN 1463-9076, E-ISSN 1463-9084, Vol. 19, nr 36, s. 25052-25058Artikel i tidskrift (Refereegranskat) Published
Abstract [en]

Non-activated charge transport has been demonstrated in terephthalate-functionalized conducting redox polymers. The transition from a temperature-activated conduction mechanism to a residual scattering mechanism was dependent on the doping level. The latter mechanism is associated with apparent negative activation barriers to charge transport and is generally found in polymer materials with a high degree of order. Crystallographic data, however, suggested a low degree of order in this polymer, indicating the existence of interconnected crystal domains in the predominantly amorphous polymer matrix through which the charge was transported. We have thus shown that the addition of bulky pendant groups to conducting polymers does not prevent efficient charge transport via the residual scattering mechanism with low barriers to charge transport.

Ort, förlag, år, upplaga, sidor
Royal Society of Chemistry, 2017
Nationell ämneskategori
Nanoteknik
Forskningsämne
Teknisk fysik med inriktning mot nanoteknologi och funktionella material
Identifikatorer
urn:nbn:se:uu:diva-304625 (URN)10.1039/c7cp03939e (DOI)000411606200067 ()28879367 (PubMedID)
Forskningsfinansiär
VetenskapsrådetStiftelsen för strategisk forskning (SSF)Stiftelsen Olle Engkvist ByggmästareEU, Horisont 2020, 64431Energimyndigheten
Tillgänglig från: 2016-10-06 Skapad: 2016-10-06 Senast uppdaterad: 2018-06-04Bibliografiskt granskad
Sjödin, M., Emanuelsson, R., Sterby, M., Åkerlund, L., Huang, H., Huang, X., . . . Strömme, M. (2017). Organic Batteries Based on Quinone-Substituted Conducting Polymers. In: : . Paper presented at The 17th IUPAC International Symposium on MacroMolecular Complexes (MMC-17), Tokyo, August 28-31, 2017..
Öppna denna publikation i ny flik eller fönster >>Organic Batteries Based on Quinone-Substituted Conducting Polymers
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2017 (Engelska)Konferensbidrag, Muntlig presentation med publicerat abstract (Refereegranskat)
Nationell ämneskategori
Nanoteknik
Forskningsämne
Teknisk fysik med inriktning mot nanoteknologi och funktionella material
Identifikatorer
urn:nbn:se:uu:diva-334414 (URN)
Konferens
The 17th IUPAC International Symposium on MacroMolecular Complexes (MMC-17), Tokyo, August 28-31, 2017.
Tillgänglig från: 2017-11-23 Skapad: 2017-11-23 Senast uppdaterad: 2017-11-27Bibliografiskt granskad
Huang, X., Yang, L., Strömme, M., Sjödin, M. & Gogoll, A. (2016). 3-(3,4-ethylenedioxythiophene)prop-1-yne (pyEDOT): A new versatile building block for functionalized PEDOTs. In: 25th Organikerdagarna: . Paper presented at 25th Organikerdagarna, 14-17 June, Umeå, Sweden, 2016.
Öppna denna publikation i ny flik eller fönster >>3-(3,4-ethylenedioxythiophene)prop-1-yne (pyEDOT): A new versatile building block for functionalized PEDOTs
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2016 (Engelska)Ingår i: 25th Organikerdagarna, 2016Konferensbidrag, Poster (med eller utan abstract) (Refereegranskat)
Nationell ämneskategori
Nanoteknik
Forskningsämne
Teknisk fysik med inriktning mot nanoteknologi och funktionella material
Identifikatorer
urn:nbn:se:uu:diva-299596 (URN)
Konferens
25th Organikerdagarna, 14-17 June, Umeå, Sweden, 2016
Tillgänglig från: 2016-07-24 Skapad: 2016-07-24 Senast uppdaterad: 2016-11-30Bibliografiskt granskad
Huang, X., Yang, L., Emanuelsson, R., Bergquist, J., Strømme, M., Sjödin, M. & Gogoll, A. (2016). A versatile route to polythiophenes with functional pendant groups using alkyne chemistry. Beilstein Journal of Organic Chemistry, 12, 2682-2688
Öppna denna publikation i ny flik eller fönster >>A versatile route to polythiophenes with functional pendant groups using alkyne chemistry
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2016 (Engelska)Ingår i: Beilstein Journal of Organic Chemistry, ISSN 2195-951X, E-ISSN 1860-5397, Vol. 12, s. 2682-2688Artikel i tidskrift (Refereegranskat) Published
Abstract [en]

A new versatile polythiophene building block, 3-(3,4-ethylenedioxythiophene)prop-1-yne (pyEDOT) (3), is prepared from glycidol in four steps in 28% overall yield. pyEDOT features an ethynyl group on its ethylenedioxy bridge, allowing further functionalization by alkyne chemistry. Its usefulness is demonstrated by a series of functionalized polythiophene derivatives that were obtained by pre- and post-electropolymerization transformations, provided by the synthetic ease of the Sonogashira coupling and click chemistry.

Nyckelord
electropolymerization, functional polymers, polythiophene, Sonogashira coupling, thiophene
Nationell ämneskategori
Nanoteknik
Forskningsämne
Teknisk fysik med inriktning mot nanoteknologi och funktionella material
Identifikatorer
urn:nbn:se:uu:diva-310098 (URN)10.3762/bjoc.12.265 (DOI)000391506600001 ()
Forskningsfinansiär
Vetenskapsrådet, VR 621-2011-4423 2015-4870Stiftelsen för strategisk forskning (SSF)Energimyndigheten
Tillgänglig från: 2016-12-09 Skapad: 2016-12-09 Senast uppdaterad: 2017-11-29Bibliografiskt granskad
Yang, L., Huang, X., Gogoll, A., Strömme, M. & Sjödin, M. (2016). Conducting Redox Polymer Based Anode Materials for High Power Electrical Energy Storage. Electrochimica Acta, 204, 270-275
Öppna denna publikation i ny flik eller fönster >>Conducting Redox Polymer Based Anode Materials for High Power Electrical Energy Storage
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2016 (Engelska)Ingår i: Electrochimica Acta, ISSN 0013-4686, E-ISSN 1873-3859, Vol. 204, s. 270-275Artikel i tidskrift (Refereegranskat) Published
Abstract [en]

In this report we present the synthesis and characterization of two conducting redox polymers (CRPs) with polythiophene backbone and diethyl terephthalate pendant groups for the use as anode materials in secondary batteries. The materials show excellent rate capability allowing 301,Lm layers to be fully converted within seconds without the use of conductive additives. The high rate capability is traced to the open morphology of the materials that allows for fast ion transport, and to the mediation of electrons through the conducting polymer (CP) backbone. The requirements for the latter are i) that the redox chemistry of the pendant groups and the CP backbone overlaps and ii) that the CP conductivity is not compromised by the presence of the pendant groups. In the CRPs presented herein both these requirements are met and this is thus the first report on successful combination of the redox chemistry of organic redox molecules with the n-doping of conducting polymers.

Nyckelord
conducting redox polymers, terephthalates, polythiophene, n-doping
Nationell ämneskategori
Teknik och teknologier
Identifikatorer
urn:nbn:se:uu:diva-298055 (URN)10.1016/j.electacta.2016.03.163 (DOI)000376136700031 ()
Forskningsfinansiär
Stiftelsen för strategisk forskning (SSF)VetenskapsrådetCarl Tryggers stiftelse för vetenskaplig forskning Stiftelsen Olle Engkvist ByggmästareEnergimyndighetenEU, Horisont 2020, 644631
Tillgänglig från: 2016-07-05 Skapad: 2016-06-29 Senast uppdaterad: 2017-11-28Bibliografiskt granskad
Yang, L., Huang, X., Gogoll, A., Strømme, M. & Sjödin, M. (2016). Effect of the Linker in Terephthalate-Functionalized Conducting Redox Polymers. Electrochimica Acta, 222, 149-155
Öppna denna publikation i ny flik eller fönster >>Effect of the Linker in Terephthalate-Functionalized Conducting Redox Polymers
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2016 (Engelska)Ingår i: Electrochimica Acta, ISSN 0013-4686, E-ISSN 1873-3859, Vol. 222, s. 149-155Artikel i tidskrift (Refereegranskat) Published
Abstract [en]

Abstract The combination of high capacity redox active pendent groups and conducting polymers, realized in conducting redox polymers (CRPs), provides materials with high charge storage capacity that are electronically conducting which makes CRPs attractive for electrical energy storage applications. In this report, six polythiophene and poly(3,4-ethylenedioxythiophene)(PEDOT)-based CRPs with a diethyl terephthalate unit covalently bound to the polymer chain by various linkers have been synthesized and characterized electrochemically. The effects of the choice of polymer backbone and of the nature of the link on the electrochemistry, and in particular the cycling stability of these polymers, are discussed. All CRPs show both the doping of the polymer backbone as well as the redox behavior of the pendent groups and the redox potential of the pendent groups in the CRPs is close to that of corresponding monomer, indicating insignificant interaction between the pendant and the polymer backbone. While all CRPs show various degrees of charge decay upon electrochemical redox conversion, the PEDOT-based CRPs show significantly improved stability compared to the polythiophene counterparts. Moreover, we show that by the right choice of link the cycling stability of diethyl terephthalate substituted PEDOT-based CRPs can be significantly improved.

Nyckelord
conducting redox polymers, PEDOT, polythiophene, terephthalate
Nationell ämneskategori
Nanoteknik
Forskningsämne
Teknisk fysik med inriktning mot nanoteknologi och funktionella material
Identifikatorer
urn:nbn:se:uu:diva-310464 (URN)10.1016/j.electacta.2016.10.183 (DOI)000392566200018 ()
Forskningsfinansiär
Stiftelsen för strategisk forskning (SSF)VetenskapsrådetCarl Tryggers stiftelse för vetenskaplig forskning Stiftelsen Olle Engkvist ByggmästareEnergimyndighetenEU, Europeiska forskningsrådet, 644631
Tillgänglig från: 2016-12-16 Skapad: 2016-12-16 Senast uppdaterad: 2017-11-29Bibliografiskt granskad
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