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Díaz-Álvarez, Alba Estrella
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Publications (2 of 2) Show all publications
Díaz-Álvarez, A. E., Mesas-Sánchez, L. & Dinér, P. (2013). Nichtenzymatische dynamische kinetische Racematspaltung sekundärer Arylalkohole: planar-chirale Ferrocen- und Rutheniumkatalysatoren im Zusammenspiel. Angewandte Chemie, 125(2), 522-524
Open this publication in new window or tab >>Nichtenzymatische dynamische kinetische Racematspaltung sekundärer Arylalkohole: planar-chirale Ferrocen- und Rutheniumkatalysatoren im Zusammenspiel
2013 (English)In: Angewandte Chemie, ISSN 1521-3757, Vol. 125, no 2, p. 522-524Article in journal (Refereed) Published
Keywords
Acylierungen, Chiralität, Kinetische Racematspaltung, Sekundäre Alkohole
National Category
Organic Chemistry
Identifiers
urn:nbn:se:uu:diva-189455 (URN)10.1002/ange.201207648 (DOI)
Available from: 2013-01-02 Created: 2013-01-02 Last updated: 2013-08-20Bibliographically approved
Mesas-Sánchez, L., Díaz-Álvarez, A. E. & Dinér, P. (2013). Non-enzymatic kinetic resolution of 1,2-azidoalcohols using a planar-chiral DMAP derivative catalyst. Tetrahedron, 69(2), 753-757
Open this publication in new window or tab >>Non-enzymatic kinetic resolution of 1,2-azidoalcohols using a planar-chiral DMAP derivative catalyst
2013 (English)In: Tetrahedron, ISSN 0040-4020, E-ISSN 1464-5416, Vol. 69, no 2, p. 753-757Article in journal (Refereed) Published
Abstract [en]

Optically pure 1,2-azidoalcohols are widely used as precursors for other high value organic products. A non-enzymatic kinetic resolution procedure for the stereoselective synthesis of chiral 1,2-azidoalcohols from the readily available racemic counterparts has been developed, employing a planar-chiral DMAP derivative catalyst. Following this procedure, a range of aromatic 1,2-azidoalcohols was obtained in good selectivities (up to S=45) and high enantiomeric excess (up to 99% ee).

Keywords
Non-enzymatic kinetic resolution, 1, 2-Azidoalcohols, Planar-chiral DMAP derivative catalyst, Ferrocenyl catalyst
National Category
Organic Chemistry
Identifiers
urn:nbn:se:uu:diva-189450 (URN)10.1016/j.tet.2012.10.077 (DOI)000314371800045 ()
Available from: 2013-01-02 Created: 2013-01-02 Last updated: 2017-12-06Bibliographically approved
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