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Wagner, Andreas
Publications (1 of 1) Show all publications
Fei, H., Pullen, S., Wagner, A., Ott, S. & Cohen, S. M. (2015). Functionalization of robust Zr(IV)-based metal-organic framework films via a postsynthetic ligand exchange. Chemical Communications, 51(1), 66-69
Open this publication in new window or tab >>Functionalization of robust Zr(IV)-based metal-organic framework films via a postsynthetic ligand exchange
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2015 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, Vol. 51, no 1, p. 66-69Article in journal (Refereed) Published
Abstract [en]

A facile and efficient fabrication approach for homogeneous, crack-free UiO-66 films with exceptionally high crystallinity and tunable thickness on a transparent and conductive glass substrate is reported. Two functionalized species, a catechol ligand and a Fe-2 complex with structural resemblance to the active site of [FeFe] hydrogenase, were introduced into the MOF films via a postsynthetic exchange. Voltammetric studies show the [FeFe] complex in the thinner UiO-66 films (2-5 mu m) can be reduced electrochemically.

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Chemical Sciences
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urn:nbn:se:uu:diva-241388 (URN)10.1039/c4cc08218d (DOI)000345909400008 ()25364799 (PubMedID)
Available from: 2015-01-26 Created: 2015-01-12 Last updated: 2017-12-05Bibliographically approved
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