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Publications (10 of 11) Show all publications
Granqvist, C. G., Arvizu, M. A., Qu, H.-Y., Wen, R.-T. & Niklasson, G. (2019). Advances in electrochromic device technology: Multiple roads towards superior durability. Paper presented at 61st Annual Technical Conference of the Society-of-Vacuum-Coaters (SVC), MAY 05-10, 2018 , Orlando, FL, USA.. Surface & Coatings Technology, 357, 619-625
Open this publication in new window or tab >>Advances in electrochromic device technology: Multiple roads towards superior durability
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2019 (English)In: Surface & Coatings Technology, ISSN 0257-8972, E-ISSN 1879-3347, Vol. 357, p. 619-625Article in journal (Refereed) Published
Abstract [en]

Most electrochromic (EC) devices must have a service lifetime of many years, and this is particularly so for“smart windows” in buildings with good energy efficiency and indoor comfort. The central part of oxide-based EC devices contains thin films based on W oxide and Ni oxide together with an interposed electrolyte. Depending on operating conditions, these films may show degradation at a slower or faster pace, and means to prevent or reverse this phenomenon, or as a minimum allow reliable lifetime prediction, have been sought ever since the beginnings of EC technology. Here we survey recent endeavors related to EC films of W oxide and Ni oxide and show that (i) electrochemical pretreatment of films in a liquid electrolyte can significantly improve durability, (ii)electrochemical posttreatment in a liquid electrolyte can rejuvenate degraded films, (iii) mixed oxides can have better durability and optical performance than corresponding pure oxides, and (iv) lifetime prediction is possible.

Place, publisher, year, edition, pages
Elsevier, 2019
National Category
Materials Chemistry
Research subject
Engineering Science with specialization in Solid State Physics
Identifiers
urn:nbn:se:uu:diva-369882 (URN)10.1016/j.surfcoat.2018.10.048 (DOI)000455691100083 ()
Conference
61st Annual Technical Conference of the Society-of-Vacuum-Coaters (SVC), MAY 05-10, 2018 , Orlando, FL, USA.
Funder
EU, European Research Council, 267234
Available from: 2018-12-17 Created: 2018-12-17 Last updated: 2019-02-05Bibliographically approved
Arvizu, M. A., Qu, H.-Y., Cindemir, U., Qiu, Z., Rojas González, E. A., Primetzhofer, D., . . . Niklasson, G. (2019). Electrochromic WO3 thin films attain unprecedented durability by potentiostatic pretreatment. Journal of Materials Chemistry A, 7(6), 2908-2918
Open this publication in new window or tab >>Electrochromic WO3 thin films attain unprecedented durability by potentiostatic pretreatment
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2019 (English)In: Journal of Materials Chemistry A, ISSN 2050-7488, Vol. 7, no 6, p. 2908-2918Article in journal (Refereed) Published
Abstract [en]

Electrochromic windows and glass facades are able to impart energy efficiency jointly with indoor comfort and convenience. Long-term durability is essential for practical implementation of this technology and has recently attracted broad interest. Here we show that a simple potentiostatic pretreatment of sputterdeposited thin films of amorphous WO3-the most widely studied electrochromic material-can yield unprecedented durability for charge exchange and optical modulation under harsh electrochemical cycling in a Li-ion-conducting electrolyte and effectively evades harmful trapping of Li. The pretreatment consisted of applying a voltage of 6.0 V vs. Li/Li+ for several hours to a film backed by a transparent conducting In2O3: Sn layer. Associated compositional and structural modifications were probed by several techniques, and improved durability was associated with elemental intermixing at the WO3/ITO and ITO/glass boundaries as well as with carbonaceous solid-electrolyte interfacial layers on the WO3 films. Our work provides important new insights into long-term durability of ion-exchange-based devices.

Place, publisher, year, edition, pages
ROYAL SOC CHEMISTRY, 2019
National Category
Materials Chemistry
Identifiers
urn:nbn:se:uu:diva-378529 (URN)10.1039/c8ta09621j (DOI)000457893400054 ()
Funder
EU, European Research Council, 267234Swedish Research Council, 821-2012-5144Swedish Research Council, 2017-00646_9Swedish Foundation for Strategic Research , RIF14-0053
Available from: 2019-03-22 Created: 2019-03-22 Last updated: 2019-03-22Bibliographically approved
Qu, H.-Y., Rojas-González, E. A., Granqvist, C. G. & Niklasson, G. A. (2019). Potentiostatically pretreated electrochromic tungsten oxide films with enhanced durability: Electrochemical processes at interfaces of indium–tin oxide. Thin Solid Films, 682, 163-168
Open this publication in new window or tab >>Potentiostatically pretreated electrochromic tungsten oxide films with enhanced durability: Electrochemical processes at interfaces of indium–tin oxide
2019 (English)In: Thin Solid Films, ISSN 0040-6090, E-ISSN 1879-2731, Vol. 682, p. 163-168Article in journal (Refereed) Published
Abstract [en]

Recent work has shown that electrochromic WO3 films, backed by In2O3:Sn (ITO) and immersed in a lithium-ion-conducting electrolyte, can attain unprecedented electrochemical cycling durability after potentiostatic pretreatment at high voltage. Here we demonstrate that this intriguing feature is associated with changes in the properties of the ITO film. Specifically, we studied thin films of ITO and WO3/ITO immersed in an electrolyte of LiClO4 in propylene carbonate at potentials up to 6.0 V vs. Li/Li+ by cyclic voltammetry and impedance spectroscopy and present evidence that electrochemical reactions occur under these conditions. X-ray photoemission spectroscopy indicated that the ITO film was partly dissolved at high voltages and that the dissolution reaction promoted diffusion of In and Sn into the WO3 film.

Keywords
Indium-tin oxide, Electrochemistry, Dissolution reaction, Tungsten oxide, Electrochromism
National Category
Other Materials Engineering
Research subject
Engineering Science with specialization in Solid State Physics
Identifiers
urn:nbn:se:uu:diva-385819 (URN)10.1016/j.tsf.2019.02.027 (DOI)000468626200023 ()
Funder
Swedish Research Council, VR-2016-03713
Note

De 2 första författarna delar förstaförfattarskapet.

Available from: 2019-06-17 Created: 2019-06-17 Last updated: 2019-12-06Bibliographically approved
Qu, H.-Y., Primetzhofer, D., Qiu, Z., Österlund, L., Granqvist, C. G. & Niklasson, G. (2018). Cation/Anion-based electrochemical degradation and rejuvenation of electrochromic nickel oxide films. ChemElectroChem, 5(22), 3548-3556
Open this publication in new window or tab >>Cation/Anion-based electrochemical degradation and rejuvenation of electrochromic nickel oxide films
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2018 (English)In: ChemElectroChem, ISSN 2196-0216, Vol. 5, no 22, p. 3548-3556Article in journal (Refereed) Published
Abstract [en]

Ni oxide thin films are widely used in electrochromic (EC) devices with variable throughput of visible light and solarenergy. However, the mechanisms underlying the optical modulation – and its degradation under extended operationand subsequent rejuvenation – are poorly understood especially for Li+-conducting electrolytes. Here, we report a comprehensive study of the EC properties of sputter-deposited Ni oxide films immersed in an electrolyte of LiClO4 in propylene carbonate. Cyclic voltammetry and optical transmittance measurements were used to document degradation and subsequent potentiostatic rejuvenation. X-ray diffraction did not show evidence for accompanying changes in crystallinity, whereas vibrational spectroscopy indicated that degraded films had carbonaceous surface layers. Time-of-flight elastic recoil detection analysis demonstrated that both Li+ and Cl-based ions participate in the electrochromism and its degradation and rejuvenation. A major result was that degradation is associated with a reduced difference in the concentrations of Li+ and Cl based ions in the nickel oxide during extended electrochemical cycling, and rejuvenation of degraded films is achieved by removal of Li+ ions and accumulation of Cl-based anions to regain their initial concentration difference. Our work provides new insights into the use of ion-exchange-based devices incorporating nickel oxide.

Keywords
electrochromism, degradation, nickel oxide film, rejuvenation, ToF-ERDA
National Category
Physical Chemistry Condensed Matter Physics Other Engineering and Technologies not elsewhere specified
Research subject
Engineering Science with specialization in Solid State Physics
Identifiers
urn:nbn:se:uu:diva-368950 (URN)10.1002/celc.201800791 (DOI)000450042200027 ()
Funder
Swedish Research Council, 821-2012-5144Swedish Research Council, VR-2016-03713Swedish Foundation for Strategic Research , SSF-RIF14-0053
Available from: 2018-12-10 Created: 2018-12-10 Last updated: 2019-03-19Bibliographically approved
Rojas González, E. A., Qu, H.-Y., Granqvist, C. G. & Niklasson, G. (2018). Electrochemical impedance spectroscopy analysis of Indium-Tin oxide films at high applied potentials. In: IS-TCMs: 7^th International Symposium on Transparent Conductive Materials and 4^th E-MRS & MRS-J Bilateral Symposium on Advanced Oxides and Wide Bandgap Semiconductors, Chania Crete Grekland. Paper presented at 7^th International Symposium on Transparent Conductive Materials and 4^th E-MRS & MRS-J Bilateral Symposium on Advanced Oxides and Wide Bandgap Semiconductors, Chania Crete Greece, Oct 14-19, 2018 (pp. 223). , Article ID PS1-33.
Open this publication in new window or tab >>Electrochemical impedance spectroscopy analysis of Indium-Tin oxide films at high applied potentials
2018 (English)In: IS-TCMs: 7^th International Symposium on Transparent Conductive Materials and 4^th E-MRS & MRS-J Bilateral Symposium on Advanced Oxides and Wide Bandgap Semiconductors, Chania Crete Grekland, 2018, p. 223-, article id PS1-33Conference paper, Poster (with or without abstract) (Refereed)
Abstract [en]

Indium-tin oxide (ITO) coated substrates are readily used as transparent conductors in energy-related applications like photovoltaics and smart window technology. Recently, it has been reported that electrochemical treatments at high applied voltages can enhance the durability of electrochromic (EC) films [1], and in addition rejuvenate already degraded films [2]. However, the EC electrode consists of an EC film on a transparent conductor, usually ITO, and changes in the ITO film may affect the durability and rejuvenation properties of the system. In a Li+-containing electrolyte, the safe potential range of ITO is 2-4 V vs. Li/Li+. At low potentials below 2 V vs. Li/Li+ Li compounds will form and result in a color change of ITO [3]. However, the behavior of ITO in Li+-containing electrolyte at high potentials up to 6 V vs. Li/Li+ is to our knowledge virtually unknown.   

In this work, ITO coated glass substrates with nominal sheet resistance of 60 Ω/sq, and 15 Ω/sq, having thicknesses of 50 nm, and 150 nm, respectively were used as working electrodes (WE) in a three-electrode electrochemical cell. Lithium foils were used both as counter and reference electrodes in an electrolyte consisting of 1 M LiClO4 dissolved in propylene carbonate.

A potentiostatic pretreatment at 6 V vs Li/Li+ during 24 h was applied on the WE. The current during the pretreatment showed an initial rapid decrease followed by a plateau, after which it decreased ~2 orders of magnitude. The width of the plateau for the 15 Ω/sq film was ~3 times longer than for the 60  Ω/sq film, which correlates to their thickness ratio. Cyclic voltammetry between 3.5 V and 6 V vs. Li/Li+ showed a significant current response only for potentials above 5 V for an as-deposited sample, and very little activity for a pretreated WE. The latter result indicates that the film had been stabilized by the pre-treatment.

Electrochemical impedance spectroscopy (EIS) spectra were measured at pseudo equilibrium potentials from 3.5 V vs. Li/Li+, and up to 6 V vs. Li/Li+. The spectra were modeled and fitted in terms of equivalent circuits. The spectra for potentials below 5 V were dominated by a blocking electrode response, whereas for higher voltages a low-frequency response was identified as being due to an electrochemical reaction which becomes more intense as the potential is increased. In addition the high frequency series resistance, mainly due to the ITO, is increased at high voltages and after pretreatment. Supplementary investigations by Scanning electron microscopy and X-ray photoelectron spectroscopy gave evidence for a smaller film thickness and a significantly decreased In content in films exposed to treatments at high potentials.

A better understanding of the effects of high applied potentials on transparent conductors like ITO will help to unravel mechanisms of durability enhancement and rejuvenation, and may provide guidelines for designing new procedures to enhance the durability of EC systems for energy-efficient smart windows.

 

1. M.A. Arvizu, H.-Y Qu, G.A. Niklasson and C.G. Granqvist, Thin Solid Films 653 (2018) 1-3.

2. R.-T. Wen, G.A. Niklasson and C.G. Granqvist, Nature Materials, 14 (2015) 996-1001.

3. P.M.M.C. Bressers and E.A. Meulenkamp, J. Electrochem. Soc. 145 (1998) 2225-2230.

National Category
Engineering and Technology
Research subject
Engineering Science with specialization in Solid State Physics
Identifiers
urn:nbn:se:uu:diva-369143 (URN)
Conference
7^th International Symposium on Transparent Conductive Materials and 4^th E-MRS & MRS-J Bilateral Symposium on Advanced Oxides and Wide Bandgap Semiconductors, Chania Crete Greece, Oct 14-19, 2018
Available from: 2018-12-11 Created: 2018-12-11 Last updated: 2018-12-17
Arvizu, M. A., Qu, H.-Y., Niklasson, G. A. & Granqvist, C. G. (2018). Electrochemical pretreatment of electrochromic WO3 films gives greatly improved cycling durability. Thin Solid Films, 653, 1-3
Open this publication in new window or tab >>Electrochemical pretreatment of electrochromic WO3 films gives greatly improved cycling durability
2018 (English)In: Thin Solid Films, ISSN 0040-6090, E-ISSN 1879-2731, Vol. 653, p. 1-3Article in journal (Refereed) Published
Abstract [en]

Electrochromic WO3 thin films have important applications in devices such as smart windows for energy-efficient buildings. Long-term electrochemical cycling durability of these films is essential and challenging. Here we investigate reactively sputter-deposited WO3 films, backed by indium-tin oxide layers and immersed in electrolytes of LiClO4 in propylene carbonate, and demonstrate unprecedented electrochemical cycling durability after straight-forward electrochemical pretreatments by the application of a voltage of 6 V vs. Li/Li+ for several hours.

Place, publisher, year, edition, pages
ELSEVIER SCIENCE SA, 2018
National Category
Materials Chemistry Engineering and Technology
Research subject
Engineering Science with specialization in Solid State Physics
Identifiers
urn:nbn:se:uu:diva-352465 (URN)10.1016/j.tsf.2018.02.032 (DOI)000429409800001 ()
Funder
Swedish Research Council, 821-2012-5144]EU, FP7, Seventh Framework Programme, 267234Swedish Foundation for Strategic Research , RIF14-0053
Available from: 2018-06-07 Created: 2018-06-07 Last updated: 2020-04-16Bibliographically approved
Niklasson, G., Abatte, L., Rojas González, E. A., Arvizu, M. A., Qu, H.-Y. & Granqvist, C. G. (2018). Electrochemical rejuvenation of Tungsten oxide electrochromic thin films: Evidence from impedance spectroscopy. In: 13th International Meeting on Electrochromism, IME-13: Book of Abstracts. Paper presented at 13th International Meeting on Electrochromism, Chiba University, Chiba, Japan, Aug 27-31, 2018 (pp. 11). , Article ID IN-3.
Open this publication in new window or tab >>Electrochemical rejuvenation of Tungsten oxide electrochromic thin films: Evidence from impedance spectroscopy
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2018 (English)In: 13th International Meeting on Electrochromism, IME-13: Book of Abstracts, 2018, p. 11-, article id IN-3Conference paper, Oral presentation with published abstract (Refereed)
Abstract [en]

A major challenge for energy-efficient smart window technology is to ensure the durability of electrochromic (EC) devices capable of render a service life significantly higher than 20 years. The development of more durable EC materials would also make it possible to increase the transmittance contrast between bleached and colored states without the risk of limiting service life. Recently, it has been shown that degraded EC coatings can be restored to their initial state by electrochemical rejuvenation treatments.1,2 In addition, it was found that tungsten oxide EC films could gain vastly improved durability after extended electrochemical treatments at high applied potentials.3 In this paper we present an attempt to unravel the complex mechanisms behind high potential rejuvenation and durability-enhancing treatments. We study EC amorphous tungsten oxide, which is the most commonly used EC oxide. It is used in most commercial device designs, often in combination with a nickel oxide-based complementary EC layer.

Amorphous tungsten oxide thin films were deposited by sputtering onto conducting indium-tin oxide (ITO) coated glass substrates. Ion intercalation and diffusion in the films were studied by electrochemical impedance spectroscopy measurements in the frequency range 10 mHz-10 kHz and for potentials between 2.0 and 3.3 V vs. Li/Li+, using the film as working electrode in a Li+ containing electrolyte. Measurements were carried out for as-deposited EC tungsten oxide films, degraded and rejuvenated films as well as durability-enhanced WOx films. The impedance data were in good agreement with a Randles-type equivalent circuit containing an anomalous diffusion element.4 In this study we focus on changes at the electrolyte/EC film and EC film/ITO interfaces during degradation and after different electrochemical treatments.

The most notable changes were associated with the high frequency and charge transfer resistances. The high frequency resistance increased significantly during degradation as well as extended rejuvenation treatments; a similar effect was observed in durability-enhanced WOx films. This might indicate compositional or chemical changes in the ITO backing or at the film/ITO interface. The charge transfer resistance associated with the electrolyte/film interface also increased after treatments, but in addition exhibited a strong potential dependence. The appearance of a second high-frequency process after rejuvenation is considered to be more interesting. Possible explanations include an additional adsorption step preceding ion intercalation into the EC film, or alternatively the appearance of a solid-electrolyte interphase layer of the type commonly observed in Li-ion batteries.

Ion diffusion coefficients were not significantly different for rejuvenated EC films as compared to the as-deposited ones. On the other hand degraded films exhibited a completely different impedance response, which could be interpreted as being due to parasitic chemical reactions in the system.

An increased understanding of ageing and rejuvenation processes will facilitate the search for more durable EC materials and preliminary results suggest that interfacial characteristics may influence durability. Eventually, improved EC coatings will be important for large-scale practical application of electrochromic materials, for example in smart windows.

 

 

References

[1]     R.-T. Wen, C.G. Granqvist, G.A. Niklasson, Nature Mater., 14, 996 (2015).

[2]     H.-Y. Qu, D. Primetzhofer, M.A. Arvizu, Z. Qiu, U. Cindemir, C.G. Granqvist, G.A. Niklasson, ACS Appl. Mater. Interf., 9, 42420 (2017).

[3]     M.A. Arvizu, H.-Y. Qu, G.A. Niklasson, C.G. Granqvist, Thin Solid Films, 653, 1 (2018).

[4]     S. Malmgren, S.V. Green, G.A. Niklasson, Electrochim. Acta, 247, 252 (2017).

 

National Category
Engineering and Technology
Research subject
Engineering Science with specialization in Solid State Physics
Identifiers
urn:nbn:se:uu:diva-368961 (URN)
Conference
13th International Meeting on Electrochromism, Chiba University, Chiba, Japan, Aug 27-31, 2018
Available from: 2018-12-10 Created: 2018-12-10 Last updated: 2019-03-07Bibliographically approved
Granqvist, C. G., Arvizu, M. A., Bayrak Pehlivan, I., Qu, H.-Y., Wen, R.-T. & Niklasson, G. A. (2018). Electrochromic materials and devices for energy efficiency and human comfort in buildings: A critical review. Electrochimica Acta, 259, 1170-1182
Open this publication in new window or tab >>Electrochromic materials and devices for energy efficiency and human comfort in buildings: A critical review
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2018 (English)In: Electrochimica Acta, ISSN 0013-4686, E-ISSN 1873-3859, Vol. 259, p. 1170-1182Article, review/survey (Refereed) Published
Abstract [en]

Electrochromic (EC) materials can be integrated in thin-film devices and used for modulating optical transmittance. The technology has recently been implemented in large-area glazing (windows and glass facades) in order to create buildings which combine energy efficiency with good indoor comfort. This critical review describes the basics of EC technology, provides a case study related to EC foils for glass lamination, and discusses a number of future aspects. Ample literature references are given with the object of providing an easy entrance to the burgeoning research field of electrochromics.

Place, publisher, year, edition, pages
Elsevier, 2018
National Category
Materials Chemistry Engineering and Technology
Research subject
Engineering Science with specialization in Solid State Physics
Identifiers
urn:nbn:se:uu:diva-350203 (URN)10.1016/j.electacta.2017.11.169 (DOI)000423968600129 ()
Available from: 2018-05-08 Created: 2018-05-08 Last updated: 2020-04-14Bibliographically approved
Qu, H.-Y., Rojas González, E. A., Granqvist, C. G. & Niklasson, G. (2018). Enhanced durability of Tungsten oxide electrochromic films: Processes occurring at the Indium-Tin oxide substrate. In: IS-TCMs: 7^th International Symposium on Transparent Conductive Materials and 4^th E-MRS & MRS-J Bilateral Symposium on Advanced Oxides and Wide Bandgap Semiconductors,. Paper presented at 7^th International Symposium on Transparent Conductive Materials and 4^th E-MRS & MRS-J Bilateral Symposium on Advanced Oxides and Wide Bandgap Semiconductors, Chania Crete Greece, Oct 14-19, 2018. (pp. 215). , Article ID PS1-25.
Open this publication in new window or tab >>Enhanced durability of Tungsten oxide electrochromic films: Processes occurring at the Indium-Tin oxide substrate
2018 (English)In: IS-TCMs: 7^th International Symposium on Transparent Conductive Materials and 4^th E-MRS & MRS-J Bilateral Symposium on Advanced Oxides and Wide Bandgap Semiconductors,, 2018, p. 215-, article id PS1-25Conference paper, Poster (with or without abstract) (Refereed)
Abstract [en]

Durability is a key issue for ensuring widespread and successful use of electrochromic(EC) films in energy-efficient smart windows and also for other devices such as lithium-ionbatteries and supercapacitors. Recent results showed [1] that the durability of EC WO3 thinfilms can be greatly improved by a facile electrochemical treatment at high potentials. Glass coated with In2O3:Sn (ITO) was then used as the substrate, and here we present evidence that changes in the properties of the ITO substrate is connected with the improved durability.We deposited a ~300-nm-thick WO3 film on ITO-coated glass with a sheet resistance of 60 Ω/sq and then applied 6 V vs. Li/Li+ to pretreat the WO3 thin film for 24 h in an electrolyte of LiClO4 in propylene carbonate. After the pretreatment, the durability of the WO3 thin film was excellent even after harsh electrochemical cycling in the 1.5–4 V vs. Li/Li+ range. Scanning electron microscopy showed that the thickness of the ITO layer became smaller after the pretreatment. X-ray photoelectron spectroscopy (XPS) depth profile measurements (Fig. 1) demonstrated that the concentration of In and Sn decreased significantly after pretreatment. In addition, the depth profile indicates a significant intermixing of W and In, which even seems to extend into the underlying glass. Supplementary impedance spectroscopy measurements showed that the high-frequency resistance (mainly due to the ITO) increased significantly after the pretreatment.

We also studied the behavior of ITO films with a sheet resistance of 60 Ω/sq by cyclic voltammetry. XPS measurements verified a strong decrease of In and Sn contents as well asITO thickness when the upper potential exceeded 6 V vs. Li/Li+. We propose that these interactions between WO3 and the ITO substrate, as well as physical changes in the ITO, have a positive effect on the durability of the EC WO3 thin film. This discovery may be of interest for ITO-based electronic devices as well as for designing long-time-durable EC devices.

National Category
Engineering and Technology
Research subject
Engineering Science with specialization in Solid State Physics
Identifiers
urn:nbn:se:uu:diva-369142 (URN)
Conference
7^th International Symposium on Transparent Conductive Materials and 4^th E-MRS & MRS-J Bilateral Symposium on Advanced Oxides and Wide Bandgap Semiconductors, Chania Crete Greece, Oct 14-19, 2018.
Available from: 2018-12-11 Created: 2018-12-11 Last updated: 2018-12-17
Niklasson, G. A., Wen, R.-T., Qu, H.-Y., Arvizu, M. A. & Granqvist, C. G. (2017). Durability of electrochromic films: Aging kinetics and rejuvenation. In: ECS Transactions: . Paper presented at 231st ECS Meeting, New Orleans, May 28 - June 1, 2017 (pp. 1659-1669). Electrochemical Society, 77
Open this publication in new window or tab >>Durability of electrochromic films: Aging kinetics and rejuvenation
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2017 (English)In: ECS Transactions, Electrochemical Society, 2017, Vol. 77, p. 1659-1669Conference paper, Published paper (Refereed)
Abstract [en]

A major challenge for energy-efficient smart window technology is to ensure the durability of electrochromic (EC) devices over aservice life of more than 20 years. In this paper, we report recent results from a fundamental study of the aging kinetics of EC tungsten oxide and nickel oxide thin films and describe electrochemical rejuvenation mechanisms that are able to restore the films to their initial state. The aging kinetics displays an approximate power-law decrease of the charge capacity as a function of cycle number. This decay of charge capacity can be understood in terms of models built on so-called dispersive chemical kinetics. Tungsten oxide and nickel oxide EC films can be rejuvenated by applying a high electrochemical potential or a small constant current. Trapped ions in the bulk or at the surface of the films can be released by these procedures.

Place, publisher, year, edition, pages
Electrochemical Society, 2017
Series
ECS Transactions ; 77 (11)
National Category
Materials Engineering
Research subject
Engineering Science with specialization in Solid State Physics
Identifiers
urn:nbn:se:uu:diva-332945 (URN)10.1149/07711.1659ecst (DOI)000432420500151 ()
Conference
231st ECS Meeting, New Orleans, May 28 - June 1, 2017
Funder
Swedish Research Council, 2016-03713EU, European Research Council, 267234
Available from: 2017-11-02 Created: 2017-11-02 Last updated: 2018-08-30Bibliographically approved
Organisations
Identifiers
ORCID iD: ORCID iD iconorcid.org/0000-0002-3419-462x

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