uu.seUppsala University Publications
Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Fingerprints of electronic, spin and structural dynamics from resonant inelastic soft X-ray scattering in transient photo-chemical species
Stockholm Univ, AlbaNova Univ Ctr, Dept Phys, SE-10691 Stockholm, Sweden.
Univ Potsdam, Inst Phys & Astron, Karl Liebknecht Str 32, D-14476 Potsdam, Germany.
Helmholtz Zentrum Berlin Mat & Energie GmbH, Inst Methods & Instrumentat Synchrotron Radiat Re, D-12489 Berlin, Germany.
Univ Potsdam, Inst Phys & Astron, Karl Liebknecht Str 32, D-14476 Potsdam, Germany;Helmholtz Zentrum Berlin Mat & Energie GmbH, Inst Methods & Instrumentat Synchrotron Radiat Re, D-12489 Berlin, Germany.
Show others and affiliations
2018 (English)In: Physical Chemistry, Chemical Physics - PCCP, ISSN 1463-9076, E-ISSN 1463-9084, Vol. 20, no 10, p. 7243-7253Article in journal (Refereed) Published
Abstract [en]

We describe how inversion symmetry separation of electronic state manifolds in resonant inelastic soft X-ray scattering (RIXS) can be applied to probe excited-state dynamics with compelling selectivity. In a case study of Fe L-3-edge RIXS in the ferricyanide complex Fe(CN)(6)(3-), we demonstrate with multi-configurational restricted active space spectrum simulations how the information content of RIXS spectral fingerprints can be used to unambiguously separate species of different electronic configurations, spin multiplicities, and structures, with possible involvement in the decay dynamics of photo-excited ligand-to-metal charge-transfer. Specifically, we propose that this could be applied to confirm or reject the presence of a hitherto elusive transient Quartet species. Thus, RIXS offers a particular possibility to settle a recent controversy regarding the decay pathway, and we expect the technique to be similarly applicable in other model systems of photo-induced dynamics.

Place, publisher, year, edition, pages
Royal Society of Chemistry, 2018. Vol. 20, no 10, p. 7243-7253
National Category
Physical Chemistry
Identifiers
URN: urn:nbn:se:uu:diva-352727DOI: 10.1039/c7cp08326bISI: 000429286100052PubMedID: 29484313OAI: oai:DiVA.org:uu-352727DiVA, id: diva2:1214785
Funder
Swedish Research Council, 2015-03956EU, European Research Council, 669531 EDAXSwedish Research CouncilKnut and Alice Wallenberg Foundation, KAW-2013.0020Available from: 2018-06-07 Created: 2018-06-07 Last updated: 2018-06-07Bibliographically approved

Open Access in DiVA

fulltext(3033 kB)7 downloads
File information
File name FULLTEXT01.pdfFile size 3033 kBChecksum SHA-512
bf342579e8cf75df03a685f7d03ea54ee3198ab2d8421ee6147f10cbce3e30733253c1c3b35b7ffcf9a70e916beba25facb66bba31ca1393eb68155262ba562f
Type fulltextMimetype application/pdf

Other links

Publisher's full textPubMed

Authority records BETA

Guo, MeiyuanLundberg, Marcus

Search in DiVA

By author/editor
Guo, MeiyuanWernet, PhilippeLundberg, MarcusOdelius, Michael
By organisation
Theoretical Chemistry
In the same journal
Physical Chemistry, Chemical Physics - PCCP
Physical Chemistry

Search outside of DiVA

GoogleGoogle Scholar
Total: 7 downloads
The number of downloads is the sum of all downloads of full texts. It may include eg previous versions that are now no longer available

doi
pubmed
urn-nbn

Altmetric score

doi
pubmed
urn-nbn
Total: 21 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • ieee
  • modern-language-association
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf