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Formal water oxidation turnover frequencies from MIL-101(Cr) anchored Ru(bda) depend on oxidant concentration
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Molecular Biomimetics. Natl Inst Technol Puducherry, Dept Chem, Karaikal 609609, India.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Molecular Biomimetics.
Polish Acad Sci, Inst Nucl Phys, PL-31342 Krakow, Poland.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry. Polish Acad Sci, Inst Phys Chem, Ul Kasprzaka 44-52, PL-01224 Warsaw, Poland.ORCID iD: 0000-0003-2124-9510
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2018 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, Vol. 54, p. 7770-7773Article in journal (Refereed) Published
Abstract [en]

The molecular water oxidation catalyst [Ru(bda)(L)(2)] has been incorporated into pyridine-decorated MIL-101(Cr) metal-organic frameworks. The resulting MIL-101@Ru materials exhibit turnover frequencies (TOFs) up to ten times higher compared to the homogenous reference. An unusual dependence of the formal TOFs on oxidant concentration is observed that ultimately arises from differing amounts of catalysts in the MOF crystals being active.

Place, publisher, year, edition, pages
ROYAL SOC CHEMISTRY , 2018. Vol. 54, p. 7770-7773
National Category
Inorganic Chemistry Materials Chemistry
Identifiers
URN: urn:nbn:se:uu:diva-361265DOI: 10.1039/c8cc02300jISI: 000438237700009PubMedID: 29926035OAI: oai:DiVA.org:uu-361265DiVA, id: diva2:1255140
Funder
Swedish Research CouncilSwedish Energy AgencyKnut and Alice Wallenberg FoundationEU, European Research Council, ERC-CoG2015-681895_MOFcat
Note

De två första författarna delar förstaförfattarskapet.

Available from: 2018-10-11 Created: 2018-10-11 Last updated: 2018-10-11Bibliographically approved

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Bhunia, AsamanjoyJohnson, Ben A.Sá, JacintoOtt, Sascha

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