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Efficient visible light-driven water oxidation catalysed by an iron(IV) clathrochelate complex
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.ORCID iD: 0000-0003-2104-1912
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.ORCID iD: 0000-0003-0510-5541
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Molecular Biomimetics.ORCID iD: 0000-0002-6218-3039
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2019 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, Vol. 55, no 23, p. 3335-3338Article in journal (Refereed) Published
Abstract [en]

A water-stable FeIV clathrochelate complex catalyzes fast and homogeneous photochemical oxidation of water to dioxygen with a turnover frequency of 2.27 s−1 and a maximum turnover number of 365. An FeV intermediate generated under catalytic conditions is trapped and characterised using EPR and Mössbauer spectroscopy.

Place, publisher, year, edition, pages
2019. Vol. 55, no 23, p. 3335-3338
Keywords [en]
Artificial photosynthesis, water oxidation, iron catalyst, photochemical water oxidation, electrochemical water oxidation
National Category
Physical Chemistry
Research subject
Chemistry with specialization in Physical Chemistry
Identifiers
URN: urn:nbn:se:uu:diva-379606DOI: 10.1039/C9CC00229DISI: 000461397500002PubMedID: 30801592OAI: oai:DiVA.org:uu-379606DiVA, id: diva2:1296967
Funder
EU, Horizon 2020, 778245Swedish InstituteAvailable from: 2019-03-18 Created: 2019-03-18 Last updated: 2019-04-12Bibliographically approved

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Shylin, Sergii I.Pavliuk, Mariia V.D'Amario, LucaMamedov, FikretSá, JacintoBerggren, Gustav

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