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Structure and thermal expansion of the distorted Prussian blue analogue RbCuCo(CN)(6)
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Inorganic Chemistry. Univ Oxford, Inorgan Chem Lab, Dept Chem, South Parks Rd, Oxford OX1 3QR, England.ORCID iD: 0000-0002-8804-298x
Rutherford Appleton Lab, ISIS Facil, Harwell Campus, Didcot OX11 0QX, Oxon, England.
2019 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, Vol. 55, no 69, p. 10230-10233Article in journal (Refereed) Published
Abstract [en]

The structure and thermal expansion of the Prussian blue analogue RbCuCo(CN)(6) has been determined via neutron and X-ray powder diffraction. The system crystallises in Cccm and harbours three coexisting distortions relative to the parent Fm3m structure, which leads to anisotropic thermal expansion with a near-zero component in one direction. The difficulties associated with determining octahedral tilt systems in Prussian blue analogues and related double molecular perovskites are discussed.

Place, publisher, year, edition, pages
ROYAL SOC CHEMISTRY , 2019. Vol. 55, no 69, p. 10230-10233
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Materials Chemistry
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URN: urn:nbn:se:uu:diva-394050DOI: 10.1039/c9cc05436gISI: 000482412300002PubMedID: 31380536OAI: oai:DiVA.org:uu-394050DiVA, id: diva2:1357625
Available from: 2019-10-04 Created: 2019-10-04 Last updated: 2019-10-04Bibliographically approved

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Boström, Hanna

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