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Manganese Hexacyanomanganate as a Positive Electrode for Nonaqueous Li-, Na-, and K-Ion Batteries
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Structural Chemistry. (Ångström Advanced Battery Centre)
Stockholm Univ, Dept Mat & Environm Chem, SE-10691 Stockholm, Sweden.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Structural Chemistry. (Ångström Advanced Battery Centre)
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Structural Chemistry. (Ångström Advanced Battery Centre)ORCID iD: 0000-0003-2737-4670
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2019 (English)In: The Journal of Physical Chemistry C, ISSN 1932-7447, E-ISSN 1932-7455, Vol. 123, no 36, p. 22040-22049Article in journal (Refereed) Published
Abstract [en]

K2Mn[Mn(CN)(6)] is synthesized, characterized, and evaluated as possible positive electrode material in nonaqueous Li-, Na-, and K-ion batteries. This compound belongs to the rich and versatile family of hexacyanometallates displaying distinctive structural properties, which makes it interesting for ion insertion purposes. It can be viewed as a perovskite-like compound in which CN-bridged Mn(CN)(6) octahedra form an open framework structure with sufficiently large diffusion channels able to accommodate a variety of insertion cations. By means of galvanostatic cycling and cyclic voltammetry tests in nonaqueous alkali metal half-cells, it is demonstrated that this material is able to reversibly host Li+, Na+, and K+ ions via electrochemical insertion/deinsertion within a wide voltage range. The general electrochemical features are similar for all of these three ion insertion chemistries. An in operando X-ray diffraction investigation indicates that the original monoclinic structure is transformed into a cubic one during charging (i.e., removal of cations from the host framework) and that such a process is reversible upon subsequent cell discharge and cation reuptake.

Place, publisher, year, edition, pages
AMER CHEMICAL SOC , 2019. Vol. 123, no 36, p. 22040-22049
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Physical Chemistry Materials Chemistry
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URN: urn:nbn:se:uu:diva-395691DOI: 10.1021/acs.jpcc.9b06338ISI: 000486360900021OAI: oai:DiVA.org:uu-395691DiVA, id: diva2:1365271
Funder
Swedish Research Council, 2011-6512Swedish Energy Agency, 2017-013531StandUpÅForsk (Ångpanneföreningen's Foundation for Research and Development), 18-317Available from: 2019-10-24 Created: 2019-10-24 Last updated: 2019-10-24Bibliographically approved

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Renman, ViktorGómez, Cesar PayGustafsson, TorbjörnEdström, KristinaValvo, Mario

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