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In-situ quartz crystal microbalance investigation of atomic layer deposition of Cu3N
Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Materials Chemistry. Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Materials Chemistry, Inorganic Chemistry. oorganisk kemi.
Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Materials Chemistry, Inorganic Chemistry.
Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Materials Chemistry. Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Materials Chemistry, Inorganic Chemistry. oorganisk kemi.
2005 (English)In: Electrochemical Society v. PV 2005-09 EUROCVD-15: Fifteenth European Conference on Chemical Vapor Deposition, 2005, 591-597 p.Conference paper, Published paper (Refereed)
Place, publisher, year, edition, pages
2005. 591-597 p.
National Category
Inorganic Chemistry
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URN: urn:nbn:se:uu:diva-76384OAI: oai:DiVA.org:uu-76384DiVA: diva2:104296
Note
Cu3N is a promising material for optical data storage and copper metallisation. Upon heating the metastable Cu3N decomposes into metallic copper and nitrogen gas. Films have been grown with a novel ALD (Atomic Layer Deposition) process using copper(II) hexafluoroacetylacetonate (Cu(hfac)2), water and ammonia as precursors. By adding an intermediate water pulse the growth rate was enhanced on oxide substrates. The water was used with the purpose of producing sacrificial oxide layers. The mass changes during the deposition cycles were measured by in-situ Quartz Crystal Microbalance (QCM) technique. Extensive hfac removal was observed during Cu(hfac)2 adsorption, yielding a surface composition of Cu(hfac) 0.4 (ad) for short pulses.Available from: 2006-12-13 Created: 2006-12-13

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Ottosson, MikaelTörndahl, TobiasCarlsson, Jan-Otto

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