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Flow hydrogenation of p-nitrophenol with nano-Ag/Al2O3
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
Marie Curie Sklodowska Univ, Dept Chem Technol, Fac Chem, PL-20031 Lublin, Poland..
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Inorganic Chemistry.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry. Polish Acad Sci, Inst Phys Chem, PL-01224 Warsaw, Poland..
2016 (English)In: RSC Advances, ISSN 2046-2069, E-ISSN 2046-2069, Vol. 6, no 90, 87564-87568 p.Article in journal (Refereed) Published
Abstract [en]

Herein, we report the first continuous-flow hydrogenation of p-nitrophenol to p-aminophenol with molecular hydrogen, as a reducing agent. This reaction converts a known pollutant into a high value product with only water as a by product, which is also the solvent. We employed Ag nanoparticles (<5 nm) supported on alumina, which were synthesized directly on low surface area alumina, avoiding the need for catalyst post-processing to confer the required nominal size for flow applications.

Place, publisher, year, edition, pages
2016. Vol. 6, no 90, 87564-87568 p.
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:uu:diva-307463DOI: 10.1039/c6ra17512kISI: 000384232600096OAI: oai:DiVA.org:uu-307463DiVA: diva2:1047041
Funder
Stiftelsen Olle Engkvist Byggmästare, 2015/636Swedish Research Council, 2015-03764
Available from: 2016-11-16 Created: 2016-11-16 Last updated: 2016-11-16Bibliographically approved

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