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Preparation and use of aziridino alcohols as promoters for the enantioselective addition of dialkylzinc reagents to N-(diphenylphosphinoyl) imines
Uppsala University.
Uppsala University.
Uppsala University.
1997 (English)In: JOURNAL OF ORGANIC CHEMISTRY, Vol. 62, no 21, 7364-7375 p.Other (Other scientific)
Abstract [en]

A set of chiral aziridino alcohols 2-5 has been synthesized starting from either readily available amino acids (L-serine, L-threonine, and allo-L-threonine) or simple olefins (using Sharpless asymmetric aminohydroxylation and dihydroxylation reactions).

Place, publisher, year, pages
AMER CHEMICAL SOC , 1997. Vol. 62, no 21, 7364-7375 p.
Keyword [en]
CATALYZED ASYMMETRIC DIHYDROXYLATION; OPTICALLY-ACTIVE AMINES; CHIRAL AZIRIDINES; N-DIPHENYLPHOSPHINOYLIMINES; ORGANOLITHIUM REAGENTS; ORGANOZINC REAGENTS; SIDE-CHAIN; ALKYLATION; ALDEHYDES; CONFIGURATION
Identifiers
URN: urn:nbn:se:uu:diva-77650OAI: oai:DiVA.org:uu-77650DiVA: diva2:105562
Note
Addresses: Andersson PG, UNIV UPPSALA, DEPT ORGAN CHEM, BOX 531, S-75121 UPPSALA, SWEDEN. TECH UNIV DENMARK, DEPT ORGAN CHEM, DK-2800 LYNGBY, DENMARK.Available from: 2008-10-17 Created: 2008-10-17

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