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Stereoelectronic control on the kinetic stability of beta-acetoxy-substituted (eta(3)-allyl)palladium complexes in a mild acidic medium
Uppsala University.
Uppsala University.
Uppsala University.
1997 (English)In: ORGANOMETALLICS, Vol. 16, no 17, 3779-3785 p.Other (Other scientific)
Abstract [en]

Deuteromethanolysis of trans-and cis-beta-acetoxy-substituted (eta(3)-cyclohexylallyl)palladium complexes (1 and 2) were studied under mild acidic conditions. The trans-beta-acetoxysubstituted complex (1) reacted about 200 times faster than its cis-subst

Place, publisher, year, pages
AMER CHEMICAL SOC , 1997. Vol. 16, no 17, 3779-3785 p.
Keyword [en]
EFFECTIVE CORE POTENTIALS; MOLECULAR MECHANICS MM2; (PI-ALLYL)PALLADIUM COMPLEXES; NUCLEOPHILIC-ATTACK; TRANSITION-METAL; PI-ALLYL; PALLADIUM; 1;3-DIENES; ALKYLATIONS; ATOMS
Identifiers
URN: urn:nbn:se:uu:diva-77759OAI: oai:DiVA.org:uu-77759DiVA: diva2:105671
Note
Addresses: Szabo KJ, UNIV UPPSALA, DEPT ORGAN CHEM, BOX 531, S-75121 UPPSALA, SWEDEN.Available from: 2008-10-17 Created: 2008-10-17

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