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Application of O-2-DMSO as reoxidant in the Pd(II)-catalyzed 1,4-oxidation of 5-substituted 1,3-cyclohexadienes
Uppsala University.
Uppsala University.
Uppsala University.
1997 (English)In: ACTA CHEMICA SCANDINAVICA, Vol. 51, no 6-7, 773-777 p.Other (Other scientific)
Abstract [en]

Palladium-catalyzed oxidation of 5-substituted 1,3-cyclohexadienes carrying a nucleophilic group in the side chain employing O-2-DMSO as the oxidant gave cyclization via 1,4-addition to the 1,3-diene. The nucleophilic groups employed were tosylamido and

Place, publisher, year, pages
MUNKSGAARD INT PUBL LTD , 1997. Vol. 51, no 6-7, 773-777 p.
Keyword [en]
STEREOCONTROLLED LACTONIZATION REACTIONS; PALLADIUM-CATALYZED 1;4-ADDITION; CONJUGATED DIENES; ELECTRON-TRANSFER; 1;4-DIACETOXYLATION; CYCLIZATION; COMPLEXES; CLUSTERS; OXIDATIONS; 1;3-DIENES
Identifiers
URN: urn:nbn:se:uu:diva-77812OAI: oai:DiVA.org:uu-77812DiVA: diva2:105724
Note
Addresses: UNIV UPPSALA, DEPT ORGAN CHEM, S-75121 UPPSALA, SWEDEN.Available from: 2008-10-17 Created: 2008-10-17

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