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Nature of the interactions between polar beta-substituents and palladium in eta(3)-allylpalladium complexes - A combined experimental and theoretical study
Uppsala University.
1997 (English)In: CHEMISTRY-A EUROPEAN JOURNAL, Vol. 3, no 4, p. 592-600Other (Other scientific)
Abstract [en]

Deuteromethanolysis of six beta-methoxy-substituted eta(3)-allylpalladium complexes (1-5) was studied under the same reaction conditions. The reaction rates depend on the ring size of the cyclic complexes, on the sigma-donor/pi-acceptor nature of the anc

Place, publisher, year, pages
WILEY-V C H VERLAG GMBH , 1997. Vol. 3, no 4, p. 592-600
Keywords [en]
allyl complexes; chemoselectivity; density functional calculations; regioselectivity; stereoelectronic control; substituent effects; ASYMMETRIC CATALYTIC ALLYLATION; EFFECTIVE CORE POTENTIALS; MOLECULAR MECHANICS MM2; (PI-ALLYL)PALLADIUM COMPLEXES; TRAN
Identifiers
URN: urn:nbn:se:uu:diva-79963OAI: oai:DiVA.org:uu-79963DiVA, id: diva2:107877
Note
Addresses: Szabo KJ, UNIV UPPSALA, DEPT ORGAN CHEM, BOX 531, S-75121 UPPSALA, SWEDEN.Available from: 2008-10-17 Created: 2008-10-17

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