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Palladium-catalysed enantiodivergent synthesis of cis- and trans-4-aminocyclohex-2-enols
Uppsala University.
Uppsala University.
Uppsala University.
1997 (English)In: JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, no 4, 577-584 p.Other (Other scientific)
Abstract [en]

Enantiomerically pure cis- and trans-4-aminocyclohex-2-enols are prepared from cyclohexa-1,3-diene via (-)-cis-(1R,4S)-4-acetoxycyclohex-2-enol(-)-2a using palladium(0) chemistry, Benzylamine and diethylamine are tested in the Pd-0-catalysed allylic amin

Place, publisher, year, pages
ROYAL SOC CHEMISTRY , 1997. no 4, 577-584 p.
Keyword [en]
4-CHLOROACETOXYALK-2-ENOIC ESTERS; PALLADIUM(0)-CATALYZED REACTIONS; ENANTIOSELECTIVE SYNTHESES; ENZYMATIC ASYMMETRIZATION; MICROBIAL OXIDATION; ALLYLIC AMINATION; COMPLEXES; MECHANISM; (-)-CONDURITOL-C; TRANSFORMATIONS
Identifiers
URN: urn:nbn:se:uu:diva-80058OAI: oai:DiVA.org:uu-80058DiVA: diva2:107972
Note
Addresses: UNIV UPPSALA, DEPT ORGAN CHEM, S-75121 UPPSALA, SWEDEN.Available from: 2008-10-17 Created: 2008-10-17

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