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Central versus terminal attack in nucleophilic addition to (pi-allyl)palladium complexes. Ligand effects and mechanism
Uppsala University.
Uppsala University.
Uppsala University.
Uppsala University.
1997 (English)In: ORGANOMETALLICS, Vol. 16, no 5, 1058-1064 p.Other (Other scientific)
Abstract [en]

Nucleophilic addition to (eta(3)-2-chloropropenyl)palladium complexes 1 with stabilized carbanions such as dialkyl malonates was studied. These complexes are used as probes to determine whether nucleophilic attack occurs at the central or terminal carbon

Place, publisher, year, pages
AMER CHEMICAL SOC , 1997. Vol. 16, no 5, 1058-1064 p.
Keyword [en]
EFFECTIVE CORE POTENTIALS; RAY CRYSTAL-STRUCTURE; ALLYL CARBON-ATOM; M = PD; OXODIMETHYLENEMETHANE COMPLEXES; REGIOSELECTIVITY DEPENDENCE; MOLECULAR CALCULATIONS; ETA-3-ALLYL COMPLEXES; CONJUGATED DIENES; PALLADIUM
Identifiers
URN: urn:nbn:se:uu:diva-80692OAI: oai:DiVA.org:uu-80692DiVA: diva2:108606
Note
Addresses: UNIV UPPSALA, DEPT ORGAN CHEM, S-75121 UPPSALA, SWEDEN.Available from: 2008-10-17 Created: 2008-10-17

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