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Nickel catalyzed tellurium-zinc exchange reactions. A new preparation of arylzinc reagents
Uppsala University.
Uppsala University.
Uppsala University.
Uppsala University.
1997 (English)In: TETRAHEDRON LETTERS, Vol. 38, no 6, 1005-1008 p.Other (Other scientific)
Abstract [en]

Diaryltellurides 2 and diarylditellurides 3 undergo a smooth tellurium-zinc exchange reaction in the presence of catalytic amounts of Ni(acac)(2) (5-10 mmol %) leading to arylzinc derivatives 1. The reaction can be extended to the preparation of alkylzin

Place, publisher, year, pages
PERGAMON-ELSEVIER SCIENCE LTD , 1997. Vol. 38, no 6, 1005-1008 p.
Keyword [en]
VINYLIC TELLURIDES; ASYMMETRIC-SYNTHESIS; INTRAMOLECULAR CARBOZINCATION; STEREOSELECTIVE SYNTHESIS; ORGANIC-SYNTHESIS; DIORGANOZINCS; ALDEHYDES; ALCOHOLS; IODINE; TRANSMETALATION
Identifiers
URN: urn:nbn:se:uu:diva-80739OAI: oai:DiVA.org:uu-80739DiVA: diva2:108653
Note
Addresses: UNIV UPPSALA, INST CHEM, DEPT ORGAN CHEM, S-75121 UPPSALA, SWEDEN. UNIV MARBURG, FACHBEREICH CHEM, D-35032 MARBURG, GERMANY.Available from: 2008-10-17 Created: 2008-10-17

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