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Concerted and stepwise solvolytic elimination and substitution reactions: Stereochemistry and substituent effects
Uppsala University.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry, Organic Chemistry.ORCID iD: 0000-0002-9092-261
Uppsala University.
1997 (English)In: Journal of the American Chemical Society, ISSN 0002-7863, E-ISSN 1520-5126, Vol. 119, no 6, 1217-1223 p.1217-1223 p.Article in journal (Refereed) Published
Abstract [en]

Solvolysis of the R,R and R,S isomers 2a-X and 2b-X, respectively, (X = I, Br, OBs) in 25 vol % acetonitrile in water gives the elimination products 4, 5a, and 5b along with the substitution products 2a-OH, 2b-OH, 2a-NHCOMe, and 2b-NHCOMe. The rates of e

Place, publisher, year, edition, pages
American Chemical Society (ACS), 1997. Vol. 119, no 6, 1217-1223 p.1217-1223 p.
Keyword [en]
PROMOTED E2 REACTION; AQUEOUS SOLVENT; BASE CATALYSIS; ION-PAIRS; MECHANISMS; DEPROTONATION; SPECTROSCOPY; DERIVATIVES; BORDERLINE; E1CB
National Category
Natural Sciences Organic Chemistry
Research subject
Chemistry
Identifiers
URN: urn:nbn:se:uu:diva-80759DOI: 10.1021/ja962469tOAI: oai:DiVA.org:uu-80759DiVA: diva2:108673
Note

Addresses: UNIV UPPSALA, INST CHEM, S-75121 UPPSALA, SWEDEN.

Available from: 2008-10-17 Created: 2008-10-17 Last updated: 2017-06-12

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Gogoll, Adolf

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