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Tetrahydrofuran derivatives from epoxides via group transfer cyclization or reductive radical cyclization of organotellurium and organoselenium intermediates
Uppsala University.
Uppsala University.
1997 (English)In: JOURNAL OF ORGANIC CHEMISTRY, Vol. 62, no 1, 157-173 p.Other (Other scientific)
Abstract [en]

Monosubstituted epoxides were regiospecifically ring-opened from the sterically least hindered side by benzenetellurolate and benzeneselenolate reagents to afford aryl P-hydroxyalkyl tellurides and selenides, respectively. These materials were O-allylate

Place, publisher, year, pages
AMER CHEMICAL SOC , 1997. Vol. 62, no 1, 157-173 p.
Keyword [en]
ATOM-TRANSFER CYCLIZATION; C BOND FORMATION; METHYLENE-GAMMA-BUTYROLACTONES; TRANSFER ADDITION-REACTIONS; SYNTHETIC ROUTE; RING-CLOSURE; STEREOSELECTIVE SYNTHESIS; ACYL TELLURIDES; CHAIN-REACTIONS; VINYLIC TELLURIDES
Identifiers
URN: urn:nbn:se:uu:diva-80790OAI: oai:DiVA.org:uu-80790DiVA: diva2:108704
Note
Addresses: Engman L, UNIV UPPSALA, INST CHEM, DEPT ORGAN CHEM, BOX 531, S-75121 UPPSALA, SWEDEN.Available from: 2008-10-17 Created: 2008-10-17

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