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Evaluation of two- and three-dimensional electrode platforms for the electrochemical characterization of organometallic catalysts incorporated in non-conducting metal-organic frameworks
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Molecular Biomimetics.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Molecular Biomimetics.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Molecular Biomimetics.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Physical Chemistry.
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2017 (English)In: Dalton Transactions, ISSN 1477-9226, E-ISSN 1477-9234, Vol. 46, no 15, 4907-4911 p.Article in journal (Refereed) Published
Abstract [en]

The development of a reliable platform for the electrochemical characterization of a redox-active molecular diiron complex, [FeFe], immobilized in a non-conducting metal organic framework (MOF), UiO-66, based on glassy-carbon electrodes is reported. Voltammetric data with appreciable current responses can be obtained by the use of multiwalled carbon nanotubes (MWCNT) or mesoporous carbon (CB) additives that function as conductive scaffolds to interface the MOF crystals in "three-dimensional" electrodes. In the investigated UiO-66-[FeFe] sample, the low abundance of [FeFe] in the MOF and the intrinsic insulating properties of UiO-66 prevent charge transport through the framework, and consequently, only [FeFe] units that are in direct physical contact with the electrode material are electrochemically addressable.

Place, publisher, year, edition, pages
ROYAL SOC CHEMISTRY , 2017. Vol. 46, no 15, 4907-4911 p.
National Category
Inorganic Chemistry Organic Chemistry
Identifiers
URN: urn:nbn:se:uu:diva-321800DOI: 10.1039/c7dt00578dISI: 000398888700006PubMedID: 28345708OAI: oai:DiVA.org:uu-321800DiVA: diva2:1094776
Funder
Swedish Research CouncilSwedish Energy AgencyKnut and Alice Wallenberg FoundationWenner-Gren FoundationsEU, European Research Council, ERC-CoG2015-681895_MOFcat
Available from: 2017-05-11 Created: 2017-05-11 Last updated: 2017-05-11Bibliographically approved

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Mijangos, EdgarRoy, SouvikPullen, SonjaLomoth, ReinerOtt, Sascha
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