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Advances in transition-metal-catalyzed synthesis of 3-substituted isocoumarins
Quaid I Azam Univ, Dept Chem, Islamabad 45320, Pakistan..
Quaid I Azam Univ, Dept Chem, Islamabad 45320, Pakistan..
Quaid I Azam Univ, Dept Chem, Islamabad 45320, Pakistan..
Quaid I Azam Univ, Dept Chem, Islamabad 45320, Pakistan..
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2017 (English)In: Journal of Organometallic Chemistry, ISSN 0022-328X, E-ISSN 1872-8561, Vol. 834, 88-103 p.Article, review/survey (Refereed) Published
Abstract [en]

3-Substituted isocoumarins are the most abundant class of naturally isocoumarins, found in several biologically active scaffolds and are precursors towards complex natural products. Considerable attempts have been devoted to the synthesis of these isocoumarins both by metal free or transition-metalcatalyzed reactions. Among the metal catalyzed reactions, the use of palladium, copper, gold, iron, nickel, rhodium, ruthenium, zinc, chromium, iridium, silver or thallium salts/complexes for the construction of 3-substituted isocoumarin ring is noteworthy due to being economical and good functional group tolerance. The current review focusses the recent reports on the Pd-, Cu-, Ag-, Fe-, Ni-, Rh-, Ru-, Zn, Cr-, Ir-, Ag- and Ti -catalyzed synthesis of isocoumarins.

Place, publisher, year, edition, pages
ELSEVIER SCIENCE SA , 2017. Vol. 834, 88-103 p.
Keyword [en]
Isocoumarins synthesis, Transition-metal-catalyzed reactions, 3-Substituted isocoumarins, Palladium-catalyzed synthesis of isocoumarins, Copper-catalyzed synthesis of isocoumarins
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:uu:diva-321548DOI: 10.1016/j.jorganchem.2017.02.016ISI: 000398439800011OAI: oai:DiVA.org:uu-321548DiVA: diva2:1094891
Available from: 2017-05-11 Created: 2017-05-11 Last updated: 2017-05-11Bibliographically approved

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