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Polycarbonates as alternative electrolyte host materials for solid-state sodium batteries
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Structural Chemistry.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Structural Chemistry.
Univ Minho, Ctr Quim, P-4710057 Braga, Portugal..
Univ Minho, Ctr Quim, P-4710057 Braga, Portugal..
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2017 (English)In: Electrochemistry communications, ISSN 1388-2481, E-ISSN 1873-1902, Vol. 77, 58-61 p.Article in journal (Refereed) Published
Abstract [en]

This paper describes the first implementation of the aliphatic polycarbonate PTMC- that has previously been successfully applied to lithium polymer batteries- as a non-polyether host matrix in solid-state sodium batteries. Despite higher glass transition temperatures of PTMC-NaTFSI and PTMC-NaClO4 electrolytes than their Li-containing counterparts, the ionic conductivities were found to be similar to the equivalent Li salt electrolytes. Finally, the functionality of PTMC-NaTESI was demonstrated through cycling of Na/Prussian blue half-cells displaying high discharge capacities and limited polarization at C/10 and 60 degrees C.

Place, publisher, year, edition, pages
ELSEVIER SCIENCE INC , 2017. Vol. 77, 58-61 p.
Keyword [en]
Na battery, Polymer electrolyte, Polycarbonate, Prussian blue
National Category
Chemical Engineering
Identifiers
URN: urn:nbn:se:uu:diva-321847DOI: 10.1016/j.elecom.2017.02.013ISI: 000399510400014OAI: oai:DiVA.org:uu-321847DiVA: diva2:1096671
Funder
Stiftelsen Längmanska kulturfonden
Available from: 2017-05-18 Created: 2017-05-18 Last updated: 2017-05-18Bibliographically approved

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Mindemark, JonasMogensen, RonnieBrandell, Daniel

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