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Visible-Light Photocatalysis as an Enabling Tool for the Functionalization of Unactivated C(sp(3))-Substrates
Uppsala University, Disciplinary Domain of Medicine and Pharmacy, Faculty of Pharmacy, Department of Medicinal Chemistry, Organic Pharmaceutical Chemistry.
Uppsala University, Disciplinary Domain of Medicine and Pharmacy, Faculty of Pharmacy, Department of Medicinal Chemistry, Organic Pharmaceutical Chemistry.
2017 (English)In: European Journal of Organic Chemistry, ISSN 1434-193X, E-ISSN 1099-0690, no 15, 1993-2007 p.Article, review/survey (Refereed) Published
Abstract [en]

Over the past decade, visible-light photocatalysis has emerged as one of the brightest and most dynamic fields in modern organic chemistry. By employing a transition-metal- or organic-dye-based photocatalyst in conjunction with a low-energy visible-light source, this synthetic manifold allows the facile generation of radical intermediates that can subsequently be directed through a wide range of transformations. Although initial studies focused largely on the functionalization of stabilized radical intermediates, over the past few years significant efforts have been directed towards the functionalization of challenging unactivated radical precursors. In this review we summarize the recent developments in the use of visible-light photocatalysis for the functionalization of unactivated C(sp(3))-substrates.

Place, publisher, year, edition, pages
WILEY-V C H VERLAG GMBH , 2017. no 15, 1993-2007 p.
Keyword [en]
Photocatalysis, Photochemistry, Alkyl radicals, Radical reactions, Visible light, Cross-coupling
National Category
Organic Chemistry
Identifiers
URN: urn:nbn:se:uu:diva-322303DOI: 10.1002/ejoc.201601479ISI: 000399701800004OAI: oai:DiVA.org:uu-322303DiVA: diva2:1096779
Available from: 2017-05-19 Created: 2017-05-19 Last updated: 2017-05-19Bibliographically approved

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