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Rich Coordination Chemistry of pi-Acceptor Dibenzoarsole Ligands
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Inorganic Chemistry.
Stockholm Univ, Dept Organ Chem, S-10691 Stockholm, Sweden..
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Inorganic Chemistry.ORCID iD: 0000-0001-5403-9902
2017 (English)In: Inorganic Chemistry, ISSN 0020-1669, E-ISSN 1520-510X, Vol. 56, no 8, 4504-4511 p.Article in journal (Refereed) Published
Abstract [en]

A series of dibenzoarsole (also known as 9-arsafluorene) derivatives have been prepared, and their coordination chemistry has been investigated. The different ligand topology and the arsenic substituents govern the reactivity of the ligands. We report various crystal structures of palladium and platinum complexes derived from this family of ligands. The biphenyl backbone of the bridged bidentate ligands allows very flexible coordination. We have also studied the application of an allylic Pd complex in nucleophilic substitution reactions, revealing that the benzoarsole substituent is susceptible to metal insertion.

Place, publisher, year, edition, pages
2017. Vol. 56, no 8, 4504-4511 p.
National Category
Inorganic Chemistry
Identifiers
URN: urn:nbn:se:uu:diva-322810DOI: 10.1021/acs.inorgchem.7b00100ISI: 000399625600030PubMedID: 28345894OAI: oai:DiVA.org:uu-322810DiVA: diva2:1106903
Available from: 2017-06-08 Created: 2017-06-08 Last updated: 2017-06-08Bibliographically approved

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