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The structure of Li3Cu2O4, a compound with formal mixed valence
Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Chemistry. Oorganisk kemi.
Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Chemistry. Oorganisk kemi.
1993 (English)In: J Alloys Comp, Vol. 190, 295-299 p.Article in journal (Refereed) Published
Abstract [en]

The structure of Li3Cu2O4 was solved from X-ray powder diffraction data and refined from a multiphase specimen using the Rietveld method. The cuprate crystallizes in C2/m with Z=2. The compound has a small homogeneity range. Typical parameters are a= 9.946(5) Angstrom, b= 2.778(2) Angstrom, c= 7.260(5) Angstrom and beta= 119.10(2) degrees. The structure may be described as an ordered intergrowth of slabs of Li2CuO2 and hypothetical LiCuO2 of NaCuO2 type. The formula suggests a copper (II,III) mixture, but there is only one crystallographic copper site

Place, publisher, year, edition, pages
1993. Vol. 190, 295-299 p.
Identifiers
URN: urn:nbn:se:uu:diva-83769OAI: oai:DiVA.org:uu-83769DiVA: diva2:111677
Note
DEPT OF INORGANIC CHEMISTRY, UNIVERSITY OF UPPSALA, BOX 531, S-751 21 UPPSALA, SWEDEN; LABORATOIRE DES FLUORURES, CNRS-URA449, UNIVERSITE DU MAINE, ROUTE DE LAVAL, 72017 LE MANS, FRANCEAvailable from: 2006-11-09 Created: 2006-11-09 Last updated: 2011-01-16

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