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Carboxylation of Alkyl Iodides with [11C] and (13C)Carbon Monoxide: Using Sulfoxides as Oxygen Nucleophiles
Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Biochemistry and Organic Chemistry. Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Biochemistry and Organic Chemistry, Organic Chemistry II.
Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Biochemistry and Organic Chemistry. Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Biochemistry and Organic Chemistry, Organic Chemistry II.
Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Biochemistry and Organic Chemistry. Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Biochemistry and Organic Chemistry, Organic Chemistry II.
2005 (English)In: Synlett, no 20, 3154-3156 p.Article in journal (Refereed) Published
Abstract [en]

11C-Labeled carboxylic acids were prepared from alkyl iodides and [11C]carbon monoxide by irradiation by UV light in anhydrous DMSO solutions in the presence of triethylamine. Sulfoxides other than DMSO can be used and may be used in stoichiometric amounts using inert solvents.

Place, publisher, year, edition, pages
2005. no 20, 3154-3156 p.
Keyword [en]
sulfoxides, radical reactions, carbonylations, carboxylic acid, photochemistry
National Category
Organic Chemistry
Identifiers
URN: urn:nbn:se:uu:diva-83888DOI: doi:10.1055/s-2005-922751OAI: oai:DiVA.org:uu-83888DiVA: diva2:111796
Available from: 2006-11-10 Created: 2006-11-10 Last updated: 2011-01-12

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Itsenko, OleksiyLångström, Bengt

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