Carboxylation of Alkyl Iodides with [11C] and (13C)Carbon Monoxide: Using Sulfoxides as Oxygen Nucleophiles
2005 (English)In: Synlett, no 20, 3154-3156 p.Article in journal (Refereed) Published
11C-Labeled carboxylic acids were prepared from alkyl iodides and [11C]carbon monoxide by irradiation by UV light in anhydrous DMSO solutions in the presence of triethylamine. Sulfoxides other than DMSO can be used and may be used in stoichiometric amounts using inert solvents.
Place, publisher, year, edition, pages
2005. no 20, 3154-3156 p.
sulfoxides, radical reactions, carbonylations, carboxylic acid, photochemistry
IdentifiersURN: urn:nbn:se:uu:diva-83888DOI: doi:10.1055/s-2005-922751OAI: oai:DiVA.org:uu-83888DiVA: diva2:111796