uu.seUppsala University Publications
Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • harvard1
  • ieee
  • modern-language-association
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
[FeFe] Hydrogenase active site model chemistry in a UiO-66metal-organic framework
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Molecular Biomimetics.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Molecular Biomimetics.
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Molecular Biomimetics.ORCID iD: 0000-0002-1691-729X
2017 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, Vol. 53, no 37, 5227-5230 p.Article in journal (Refereed) Published
Abstract [en]

The reactivity of [Fe-2(dcbdt)(CO)(6)] (1) confined in a UiO-66(Zr) metal-organic framework towards CO ligand substitutions with phosphines of different sizes was investigated. The reaction with smaller phosphines (PX3, X = Me, Et) is more selective compared to analogous reactions in homogenous solution phase, and two CO ligands at up to 80% of all [FeFe] sites in UiO-66-1 are replaced. The produced [Fe-2(dcbdt)(CO)(4)(PX3)(2)] complexes in the UiO-66 matrix behave like typical [FeFe] hydrogenase active site model complexes, are reduced at more cathodic potentials than their hexacarbonyl analogues, and form bridging hydrides under acidic conditions.

Place, publisher, year, edition, pages
ROYAL SOC CHEMISTRY , 2017. Vol. 53, no 37, 5227-5230 p.
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:uu:diva-325338DOI: 10.1039/c7cc01620dISI: 000400858400038PubMedID: 28443863OAI: oai:DiVA.org:uu-325338DiVA: diva2:1118020
Funder
Swedish Research CouncilSwedish Energy AgencyWenner-Gren FoundationsEU, European Research Council, ERC-CoG2015-681895_MOFcat
Available from: 2017-06-29 Created: 2017-06-29 Last updated: 2017-06-29Bibliographically approved

Open Access in DiVA

No full text

Other links

Publisher's full textPubMed

Search in DiVA

By author/editor
Pullen, SonjaRoy, SouvikOtt, Sascha
By organisation
Molecular Biomimetics
In the same journal
Chemical Communications
Chemical Sciences

Search outside of DiVA

GoogleGoogle Scholar

Altmetric score

Total: 76 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • harvard1
  • ieee
  • modern-language-association
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf