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Conformational restriction of acyclic pi-allyl ligands in (3,7-diphenyl-1,5-dimethylbispidinone)(eta(3)-alkenyl) palladium complexes
Uppsala University.
Uppsala University.
Uppsala University.
1998 (English)In: ORGANOMETALLICS, Vol. 17, no 24, 5248-5253 p.Other (Other scientific)
Abstract [en]

chelating dinitrogen ligand based on the bispidine skeleton is shown to restrict the conformational freedom of small, acyclic pi-allyl ligands in palladium complexes. The pi-allyl ligand is locked into one single rotamer by entirely steric interactions.

Place, publisher, year, pages
AMER CHEMICAL SOC , 1998. Vol. 17, no 24, 5248-5253 p.
Keyword [en]
(PI-ALLYL)PALLADIUM COMPLEXES; CONFIGURATIONAL ASSIGNMENT; PLATINUM(II) COMPLEXES; NUCLEOPHILIC-ATTACK; MOLECULAR MECHANICS; BETA-SUBSTITUENTS; NITROGEN LIGANDS; NMR; ROTATION; BONDS
Identifiers
URN: urn:nbn:se:uu:diva-84733OAI: oai:DiVA.org:uu-84733DiVA: diva2:112641
Note
Addresses: Gogoll A, Univ Uppsala, Dept Organ Chem, Box 531, S-75121 Uppsala, Sweden. Univ Uppsala, Dept Organ Chem, S-75121 Uppsala, Sweden.Available from: 2008-10-17 Created: 2008-10-17

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