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Chiral benzoquinones as a new class of ligands for asymmetric catalysis: Synthesis and application to the palladium(II)-catalyzed 1,4-dialkoxylation of 1,3-dienes
Uppsala University.
Uppsala University.
Uppsala University.
Uppsala University.
1998 (English)In: JOURNAL OF ORGANIC CHEMISTRY, Vol. 63, no 19, 6466-6471 p.Other (Other scientific)
Abstract [en]

Chiral C-2-symmetric 2,5-bisamide hydroquinone ligands, with beta-amino alcohols as chiral building units, were synthesized in excellent overall yields. The ligands gave up to 54.4% ee in the palladium-catalyzed 1,4-dialkoxylation of 1,3-dienes. These fi

Place, publisher, year, pages
AMER CHEMICAL SOC , 1998. Vol. 63, no 19, 6466-6471 p.
Keyword [en]
STEREOSELECTIVE SYNTHESIS; ACCELERATED CATALYSIS; 1;2-AMINO ALCOHOLS; CONJUGATED DIENES; ALLYLIC AMIDES; COMPLEXES; AMINOHYDROXYLATION; CYCLIZATION; EPOXIDES; OLEFINS
Identifiers
URN: urn:nbn:se:uu:diva-84739OAI: oai:DiVA.org:uu-84739DiVA: diva2:112647
Note
Addresses: Backvall JE, Stockholm Univ, Arrhenius Lab, Dept Organ Chem, S-10691 Stockholm, Sweden. Stockholm Univ, Arrhenius Lab, Dept Organ Chem, S-10691 Stockholm, Sweden. Univ Uppsala, Dept Organ Chem, S-75121 Uppsala, Sweden.Available from: 2008-10-17 Created: 2008-10-17

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