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Highly enantioselective intermolecular Cu(I)-Catalyzed cyclopropanation of cyclic enol ethers. Asymmetric total synthesis of (+)-quebrachamine
Uppsala University.
Uppsala University.
Uppsala University.
1998 (English)In: JOURNAL OF ORGANIC CHEMISTRY, Vol. 63, no 17, 6007-6015 p.Other (Other scientific)
Abstract [en]

A set of cyclic enol ethers derived from 2,3-dihydrofuran 35 and 3,4-dihydropyran 8 with a varying substitution pattern at the olefinic system were synthesized. Evans's ligand 5 with Cu(I)OTf was found to be an effective catalyst in the cyclopropanation

Place, publisher, year, pages
AMER CHEMICAL SOC , 1998. Vol. 63, no 17, 6007-6015 p.
Keyword [en]
STEREOSELECTIVE CYCLOPROPANATION; CARBOXYLIC-ACIDS; ALLYLIC ALCOHOLS; OLEFINS; CATALYST; LIGANDS; (+)-VINCAMINE; DERIVATIVES; ALKYLATION; EFFICIENT
Identifiers
URN: urn:nbn:se:uu:diva-84746OAI: oai:DiVA.org:uu-84746DiVA: diva2:112654
Note
Addresses: Andersson PG, Univ Uppsala, Dept Organ Chem, Box 531, S-75121 Uppsala, Sweden. Univ Uppsala, Dept Organ Chem, S-75121 Uppsala, Sweden.Available from: 2008-10-17 Created: 2008-10-17

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