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Acid-catalyzed solvolysis of allylic ethers and alcohols. Competing elimination and substitution via a thermodynamically "stable" carbocation
Uppsala University.
Uppsala University.
1998 (English)In: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Vol. 120, no 26, 6512-6517 p.Other (Other scientific)
Abstract [en]

Specific acid-catalyzed solvolysis of l-methoxy-l,4-dihydronaphthalene (1-OMe) or 2-methoxy-1,2-dihydronaphthalene (2-OMe) in 25 vol % acetonitrile in water yields mainly the elimination product naphthalene, which is accompanied by a trace of 2-hydroxy-1

Place, publisher, year, pages
AMER CHEMICAL SOC , 1998. Vol. 120, no 26, 6512-6517 p.
Keyword [en]
ION-MOLECULE PAIRS; NUCLEOPHILIC-SUBSTITUTION; MONOCYCLIC ARENES; 1;2-DIHYDRONAPHTHALENE; INTERMEDIATE; NAPHTHALENE; METABOLISM; MECHANISMS; SOLVENT
Identifiers
URN: urn:nbn:se:uu:diva-84756OAI: oai:DiVA.org:uu-84756DiVA: diva2:112664
Note
Addresses: Thibblin A, Univ Uppsala, Inst Chem, Box 531, S-75121 Uppsala, Sweden. Univ Uppsala, Inst Chem, S-75121 Uppsala, Sweden.Available from: 2008-10-17 Created: 2008-10-17

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