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Mechanism of palladium-catalyzed allylic acetoxylation of cyclohexene
Uppsala University.
Uppsala University.
1998 (English)In: CHEMISTRY-A EUROPEAN JOURNAL, Vol. 4, no 6, 1083-1089 p.Other (Other scientific)
Abstract [en]

The mechanism of the quinone-based palladium-catalyzed oxidation of cyclohexene to allylic acetate was studied under various reaction conditions with 1,2-dideuterocyclohexene (62-74% D) as the substrate. The reactions gave a 1:1 mixture of 1,2-dideutero-

Place, publisher, year, pages
WILEY-V C H VERLAG GMBH , 1998. Vol. 4, no 6, 1083-1089 p.
Keyword [en]
allylic oxidation; homogeneous catalysis; palladium; pi-allyl intermediates; isotopic labeling; TERT-BUTYL HYDROPEROXIDE; (PI-ALLYL)PALLADIUM COMPLEXES; NUCLEOPHILIC-ATTACK; HYDROGEN-PEROXIDE; SELENIUM DIOXIDE; OLEFINS; OXIDATION; ACIDS; ACETATES; OXIDA
Identifiers
URN: urn:nbn:se:uu:diva-84762OAI: oai:DiVA.org:uu-84762DiVA: diva2:112670
Note
Addresses: Grennberg H, Univ Uppsala, Dept Organ Chem, Box 531, SE-75121 Uppsala, Sweden. Univ Uppsala, Dept Organ Chem, SE-75121 Uppsala, Sweden.Available from: 2008-10-17 Created: 2008-10-17

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