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Using C-11/C-14 incoming group and secondary alpha-deuterium KIEs to determine how a change in leaving group alters the structure of the transition state of the S(N)2 reactions between m-chlorobenzyl para-substituted benzenesulfonates and cyanide ion
Uppsala University.
Uppsala University.
Uppsala University.
Uppsala University.
1998 (English)In: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Vol. 120, no 14, 3340-3344 p.Other (Other scientific)
Abstract [en]

The C-11/C-14 incoming group and secondary alpha-deuterium KIEs and Hammett rho value found by changing the substituent in the leaving group of the S(N)2 reactions between meta-chlorobenzyl para-substituted benzenesulfonates and cyanide ion in 0.5% aqueo

Place, publisher, year, pages
AMER CHEMICAL SOC , 1998. Vol. 120, no 14, 3340-3344 p.
Keyword [en]
MENSCHUTKIN-TYPE REACTION; SN2 REACTIONS; BENZYL BENZENESULFONATES; ISOTOPE; NITROGEN; N;N-DIMETHYLANILINES; CARBON; AMINES; MODEL
Identifiers
URN: urn:nbn:se:uu:diva-84783OAI: oai:DiVA.org:uu-84783DiVA: diva2:112691
Note
Addresses: Westaway KC, Laurentian Univ, Dept Chem & Biochem, Sudbury, ON P3E 2C6, Canada. Laurentian Univ, Dept Chem & Biochem, Sudbury, ON P3E 2C6, Canada. Univ Uppsala, Inst Chem, Dept Organ Chem, S-75121 Uppsala, Sweden.Available from: 2008-10-17 Created: 2008-10-17

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