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A versatile route to 2-substituted cyclic 1,3-dienes via a copper(I)-catalyzed cross-coupling reaction of dienyl triflates with Grignard reagents
Uppsala University.
Uppsala University.
Uppsala University.
Uppsala University.
1998 (English)In: JOURNAL OF ORGANIC CHEMISTRY, Vol. 63, no 8, 2517-2522 p.Other (Other scientific)
Abstract [en]

A general synthesis of 2-substituted cyclic 1,3-dienes in two steps from alpha,beta-unsaturated ketones has been developed. Formation of a dien-2-yl triflate followed by a copper(I)-catalyzed cross-coupling reaction with a Grignard reagent gives 2-substi

Place, publisher, year, pages
AMER CHEMICAL SOC , 1998. Vol. 63, no 8, 2517-2522 p.
Keyword [en]
OLEFIN SYNTHESIS; ENOL; TETRAHYDROPYRANS; KETONES; VINYL
Identifiers
URN: urn:nbn:se:uu:diva-84787OAI: oai:DiVA.org:uu-84787DiVA: diva2:112695
Note
Addresses: Backvall JE, Stockholm Univ, Arrhenius Lab, Dept Organ Chem, SE-10691 Stockholm, Sweden. Uppsala Univ, Dept Organ Chem, SE-75121 Uppsala, Sweden.Available from: 2008-10-17 Created: 2008-10-17

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CiteExportLink to record
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