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Unsymmetrical functionalization of 1,3-cyclohexadienes: Palladium-catalyzed stereoselective 1,4-acyloxy-alkoxylation
Uppsala University.
Uppsala University.
Uppsala University.
Uppsala University.
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1998 (English)In: TETRAHEDRON, Vol. 54, no 20, 5375-5384 p.Other (Other scientific)
Abstract [en]

Palladium-catalyzed reaction of 1,3-cyclohexadiene with alcohols and acetic or benzoic acid under mild acidic conditions gives trans-1-acetoxy- or trans-1-benzyloxy-4-alkoxy-2-cyclohexenes, respectively, with high regio-and stereo-selectivity. The unsymm

Place, publisher, year, pages
PERGAMON-ELSEVIER SCIENCE LTD , 1998. Vol. 54, no 20, 5375-5384 p.
Keyword [en]
NUCLEOPHILIC-ADDITION; 1;3-DIENES; COMPLEXES; REGIOCHEMISTRY; MECHANISM; LIGANDS
Identifiers
URN: urn:nbn:se:uu:diva-84791OAI: oai:DiVA.org:uu-84791DiVA: diva2:112699
Note
Addresses: Backvall JE, Univ Uppsala, Dept Organ Chem, Box 531, S-75121 Uppsala, Sweden. Univ Uppsala, Dept Organ Chem, S-75121 Uppsala, Sweden.Available from: 2008-10-17 Created: 2008-10-17

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