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Solvent-promoted E1cB/E2 reactions competing with stepwise solvolysis through homoallylic carbocations
Uppsala University.
Uppsala University.
1998 (English)In: JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, no 3, 583-589 p.Other (Other scientific)
Abstract [en]

The water-promoted elimination reactions of (R,S)-1-(1-X-ethyl)indene 1-X [X = Cl, Br, I, OBs (4-bromophenylsulfonyloxy)] and the corresponding (R,R) isomers 2-X in 25 vol% acetonitrile in water exhibit non-stereospecific and stereospecific 1,2 eliminati

Place, publisher, year, pages
ROYAL SOC CHEMISTRY , 1998. no 3, 583-589 p.
Keyword [en]
ELIMINATION-REACTIONS; SUBSTITUTION-REACTIONS; BASE CATALYSIS; E2 REACTION; MECHANISMS; COMMON; INTERMEDIATE; BORDERLINE; ACID
Identifiers
URN: urn:nbn:se:uu:diva-84792OAI: oai:DiVA.org:uu-84792DiVA: diva2:112700
Note
Addresses: Thibblin A, Univ Uppsala, Inst Chem, POB 531, S-75121 Uppsala, Sweden. Univ Uppsala, Inst Chem, S-75121 Uppsala, Sweden.Available from: 2008-10-17 Created: 2008-10-17

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