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Organoselenium-assisted route to conjugated dienoic macrolides. Synthesis of (Z)-Dodec-3-en-12-olide, a pheromone of the flat grain beetle Cryptolestes pusillus (Coleoptera : Cucujidae)
Uppsala University.
Uppsala University.
Uppsala University.
1999 (English)In: ACTA CHEMICA SCANDINAVICA, Vol. 53, no 8, 611-615 p.Other (Other scientific)
Abstract [en]

Oxidative elimination of the arylseleno group in (E)-2-(4-methoxyphenylseleno) dodec-4-en-12-olide gave(2Z, 4E)-dodeca-2,4-diene-12-olide which on 1,4-cis-hydrogenation over (eta(6)-naphthalene) tricarbonylchromium afforded the title pheromone. (E)-2-(4-

Place, publisher, year, pages
MUNKSGAARD INT PUBL LTD , 1999. Vol. 53, no 8, 611-615 p.
Keyword [en]
FERRULACTONE-II; STEREOCONTROLLED SYNTHESIS; AGGREGATION PHEROMONES; CONVENIENT PROTOCOL; ORGANIC-SYNTHESIS; ORYZAEPHILUS; MACROLACTONIZATION; OXIDATION; SCHONHERR; ALCOHOLS
Identifiers
URN: urn:nbn:se:uu:diva-84851OAI: oai:DiVA.org:uu-84851DiVA: diva2:112759
Note
Addresses: Serebryakov EP, ND Zelinskii Organ Chem Inst, Moscow 117913, Russia. ND Zelinskii Organ Chem Inst, Moscow 117913, Russia. Univ Uppsala, Dept Organ Chem, Inst Chem, S-75121 Uppsala, Sweden.Available from: 2008-10-17 Created: 2008-10-17

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