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Mechanisms of solvolytic elimination reactions of tertiary substrates: stereospecific 1,2-elimination reactions
Uppsala University.
Uppsala University.
1999 (English)In: JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, no 7, 1397-1404 p.Other (Other scientific)
Abstract [en]

Solvolysis of(R,S)-1-chloro-1-(fluoren-9-yl)-2-methylcyclopentane (1-Cl) or the analogous 3,5-dinitrobenzoate ester 1-DNB in largely aqueous solutions yields alkenes 1-(fluoren-9-yl)-2-methylcyclopentene (4) and 1-(fluoren-9-yl)-5-methylcyclopentene (5)

Place, publisher, year, pages
ROYAL SOC CHEMISTRY , 1999. no 7, 1397-1404 p.
Keyword [en]
ION-PAIRS; SUBSTITUTION-REACTIONS; DIARYLMETHYL CATIONS; AQUEOUS-SOLUTIONS; FLASH-PHOTOLYSIS; E2 MECHANISMS; CARBOCATION; DEPROTONATION; DERIVATIVES; TRIARYLMETHYL
Identifiers
URN: urn:nbn:se:uu:diva-84855OAI: oai:DiVA.org:uu-84855DiVA: diva2:112763
Note
Addresses: Thibblin A, Univ Uppsala, Inst Chem, Box 531, S-75121 Uppsala, Sweden. Univ Uppsala, Inst Chem, S-75121 Uppsala, Sweden.Available from: 2008-10-17 Created: 2008-10-17

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