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Dynamic kinetic resolution of secondary diols via coupled ruthenium and enzyme catalysis
Uppsala University.
Uppsala University.
Uppsala University.
1999 (English)In: JOURNAL OF ORGANIC CHEMISTRY, Vol. 64, no 14, 5237-5240 p.Other (Other scientific)
Abstract [en]

Enzymatic acylation of secondary symmetrical diols (as meso/dl mixtures) in combination with ruthenium-catalyzed isomerization of the diol led to efficient dynamic kinetic resolution. In this way, a meso/dl mixture of the diol was transformed to enantiom

Place, publisher, year, pages
AMER CHEMICAL SOC , 1999. Vol. 64, no 14, 5237-5240 p.
Keyword [en]
HYDROGENATION REACTIONS; 2;5-HEXANEDIOL; ALCOHOLS; TRANSESTERIFICATION; DERIVATIVES; ALDEHYDES; KETONES; LIGANDS
Identifiers
URN: urn:nbn:se:uu:diva-84857OAI: oai:DiVA.org:uu-84857DiVA: diva2:112765
Note
Addresses: Backvall JE, Stockholm Univ, Arrhenius Lab, Dept Organ Chem, SE-10691 Stockholm, Sweden. Stockholm Univ, Arrhenius Lab, Dept Organ Chem, SE-10691 Stockholm, Sweden. Uppsala Univ, Dept Organ Chem, SE-75121 Uppsala, Sweden.Available from: 2008-10-17 Created: 2008-10-17

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