On the transformation of T1Cu(5)Se(3) to o-T1Cu(4)Se(3)
1999 (English)In: J Alloys Comp, Vol. 288, no 1-2, 110-116 p.Article in journal (Refereed) Published
A study on the transformation of TlCu5Se3 to the metastable orthorhombic form of TlCu4Se3 upon copper leaching has been conducted using neutron powder diffraction at 10 K and 293 K. The occupancy of the various copper sites in the TlCu5Se3 structure was investigated with Rietveld profile refinement techniques in combination with elemental analysis. The results indicate that mainly one of the three copper sites in the parent compound is affected during the extraction process.
Place, publisher, year, edition, pages
1999. Vol. 288, no 1-2, 110-116 p.
thallium copper selenide; copper leaching; transformation mechanism; neutron powder diffraction; CRYSTAL-STRUCTURE; DIFFRACTION
IdentifiersURN: urn:nbn:se:uu:diva-84864OAI: oai:DiVA.org:uu-84864DiVA: diva2:112772
Addresses: Noren L, Univ Uppsala, Dept Inorgan Chem, Angstrom Lab, Box 538, S-75121 Uppsala, Sweden. Univ Uppsala, Dept Inorgan Chem, Angstrom Lab, S-75121 Uppsala, Sweden.2006-11-082006-11-082011-01-14