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Peak tailing and mass transfer kinetics in linear chromatography - Dependence on the column length and the linear velocity of the mobile phase
Uppsala University.
Uppsala University.
Uppsala University.
1999 (English)In: JOURNAL OF CHROMATOGRAPHY A, Vol. 831, no 1, 17-35 p.Other (Other scientific)
Abstract [en]

Although peak tailing in analytical (i.e., linear) chromatography is often considered to be associated merely with slow mass transfer kinetics, we show that it results rather from the use of too short a column, at too high a mobile phase velocity, under

Place, publisher, year, pages
ELSEVIER SCIENCE BV , 1999. Vol. 831, no 1, 17-35 p.
Keyword [en]
peak tailing; mass transfer kinetics; column length; mobile phase velocity; linear velocity; LIQUID-CHROMATOGRAPHY; PROPRANOLOL ENANTIOMERS; ADSORPTION BEHAVIOR; BAND PROFILES; SEPARATION; CELLULASE
Identifiers
URN: urn:nbn:se:uu:diva-84881OAI: oai:DiVA.org:uu-84881DiVA: diva2:112789
Note
Addresses: Guiochon G, Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA. Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA. Univ Uppsala, Dept Pharmaceut Analyt Chem, S-75123 Uppsala, Sweden. Oak Ridge Natl Lab, Div Chem & Analyt Sci, Oak Ridge, TN 37Available from: 2008-10-17 Created: 2008-10-17

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