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Mechanisms of elimination and substitution reactions. Spontaneous solvolysis reactions via carbanion and carbocation intermediates
Uppsala University.
Uppsala University.
Uppsala University.
1999 (English)In: JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, Vol. 12, no 2, 116-122 p.Other (Other scientific)
Abstract [en]

The reactions of 4-(4'-nitrophenyl)-4-X-butan-2-one (1-X; X = Cl, OTs) with added bases/nucleophiles exhibit second-order kinetics. These substitution and elimination reactions are concluded to be of concerted S(N)2 type and irreversible E1cB type, respe

Place, publisher, year, pages
JOHN WILEY & SONS LTD , 1999. Vol. 12, no 2, 116-122 p.
Keyword [en]
elimination reactions; substitution reactions; solvolysis reactions; carbanion intermediates; carbocation intermediates; BASE-PROMOTED ELIMINATION; AQUEOUS-SOLUTION; E2 REACTION; STEPWISE; SOLVENT; ION; DERIVATIVES; BORDERLINE; KINETICS; KETONE
Identifiers
URN: urn:nbn:se:uu:diva-84882OAI: oai:DiVA.org:uu-84882DiVA: diva2:112790
Note
Addresses: Thibblin A, Univ Uppsala, Inst Chem, POB 531, S-75121 Uppsala, Sweden. Univ Uppsala, Inst Chem, S-75121 Uppsala, Sweden.Available from: 2008-10-17 Created: 2008-10-17

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