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Access to 2,4-dien-6-ynoic acid esters using selenium chemistry. Formal synthesis of Z,Z-dodeca-3,6-dien-1-ol (trail pheromone mimic of the subterranian termite Reticulitermes virginicus) and Z,Z-dodeca-3,6-dien-11-olide (aggregation pheromone of the gra
Uppsala University.
Uppsala University.
Uppsala University.
1998 (English)In: JOURNAL OF CHEMICAL RESEARCH-S, no 11, 706-707 p.Other (Other scientific)
Abstract [en]

Esters of 2,4-dien-6-ynoic acids were prepared from terminal acetylenes by lithiation, 1,2-addition to acrolein, orthoester Claisen-Johnson rearrangement and alpha-(4-methoxyphenyl)selenation/oxidative elimination to introduce the alpha,beta-unsaturation

Place, publisher, year, pages
ROYAL SOC CHEMISTRY , 1998. no 11, 706-707 p.
Keyword [en]
STEREOCONTROLLED SYNTHESIS; CONVENIENT PROTOCOL; CRYPTOLESTES; SELENOXIDES; ELIMINATION; COLEOPTERA; CUCUJIDAE; OLEFINS
Identifiers
URN: urn:nbn:se:uu:diva-84892OAI: oai:DiVA.org:uu-84892DiVA: diva2:112800
Note
Addresses: Serebryakov EP, Russian Acad Sci, ND Zelinskii Organ Chem Inst, Moscow 117913, Russia. Russian Acad Sci, ND Zelinskii Organ Chem Inst, Moscow 117913, Russia. Univ Uppsala, Dept Organ Chem, Inst Chem, S-75121 Uppsala, Sweden.Available from: 2008-10-17 Created: 2008-10-17

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