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Palladium(II)-catalyzed 1,4-oxidation of 2-aryl-1,3-cyclohexadienes. Application to the synthesis of (+/-)-epibatidine and analogues
Uppsala University.
Uppsala University.
Uppsala University.
Uppsala University.
1999 (English)In: JOURNAL OF ORGANIC CHEMISTRY, Vol. 64, no 3, 836-842 p.Other (Other scientific)
Abstract [en]

Palladium(II)-catalyzed 1,4-chloroacetoxylation of 2-aryl-1,3-cyclohexadienes 2a and 2b resulted in a highly regio- and stereoselective reaction to give cis-1-acetoxy-3-aryl-4-chloro-2-cyclohexenes 7a and 7b, respectively. The phenyl adduct 7a was subjec

Place, publisher, year, pages
AMER CHEMICAL SOC , 1999. Vol. 64, no 3, 836-842 p.
Keyword [en]
STEREOSELECTIVE SYNTHESIS; STEREOCHEMICAL CONTROL; TROPANE ALKALOIDS; RING-SYSTEMS; EPIBATIDINE; (+)-EPIBATIDINE; (-)-EPIBATIDINE; DERIVATIVES; TRANSFORMATIONS; HYDROGENATION
Identifiers
URN: urn:nbn:se:uu:diva-84897OAI: oai:DiVA.org:uu-84897DiVA: diva2:112805
Note
Addresses: Helquist P, Univ Uppsala, Dept Organ Chem, Box 531, SE-75121 Uppsala, Sweden. Univ Uppsala, Dept Organ Chem, SE-75121 Uppsala, Sweden. Stockholm Univ, Arrhenius Lab, Dept Organ Chem, SE-10691 Stockholm, Sweden. Univ Notre Dame, Dept Chem & BioAvailable from: 2008-10-17 Created: 2008-10-17

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