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Evidence for a ruthenium dihydride species as the active catalyst in the RuCl2(PPh3)-catalyzed hydrogen transfer reaction in the presence of base
Uppsala University.
Uppsala University.
Uppsala University.
Uppsala University.
1999 (English)In: CHEMICAL COMMUNICATIONS, no 4, 351-352 p.Other (Other scientific)
Abstract [en]

The role of the base in RuCl2(PPh3)(3)-catalyzed hydrogen transfer reactions is to generate a highly active RuH2(PPh3)(3) catalyst from the dichloride via two consecutive alkoxide displacement-beta-elimination sequences.

Place, publisher, year, pages
ROYAL SOC CHEMISTRY , 1999. no 4, 351-352 p.
Keyword [en]
ENANTIOSELECTIVE TRANSFER HYDROGENATION; ASYMMETRIC TRANSFER HYDROGENATION; PHOSPHINE COMPLEXES; HIGHLY EFFICIENT; CHIRAL LIGANDS; KETONES; REDUCTION; PROPAN-2-OL; ALCOHOLS; POLYHYDRIDES
Identifiers
URN: urn:nbn:se:uu:diva-84900OAI: oai:DiVA.org:uu-84900DiVA: diva2:112808
Note
Addresses: Szabo KJ, Stockholm Univ, Dept Organ Chem, Arrhenius Lab, SE-10691 Stockholm, Sweden. Stockholm Univ, Dept Organ Chem, Arrhenius Lab, SE-10691 Stockholm, Sweden. Univ Uppsala, Dept Organ Chem, SE-75121 Uppsala, Sweden.Available from: 2008-10-17 Created: 2008-10-17

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