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A reinterpretation of the NH4Cu7S4 structure
Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Chemistry. Oorganisk kemi.
Uppsala University, Teknisk-naturvetenskapliga vetenskapsområdet, Chemistry, Department of Chemistry. Oorganisk kemi.
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1998 (English)In: J Alloys Comp, Vol. 281, no 2, 186-195 p.Article in journal (Refereed) Published
Abstract [en]

The structure of NH4Cu7-xS4 has been investigated using X-ray single crystal diffraction at varying temperatures. The room temperature structure is best described as a tetragonal crystalline framework with channels incorporating some of the copper atoms in a disordered, almost amorpjous, manner.

Place, publisher, year, edition, pages
1998. Vol. 281, no 2, 186-195 p.
Keyword [en]
ammonium thiocuprate; phase transformations; single-crystal X-ray diffraction; stoichiometry; PHASE-TRANSITIONS; TLCU7S4
Identifiers
URN: urn:nbn:se:uu:diva-84912OAI: oai:DiVA.org:uu-84912DiVA: diva2:112820
Note
Addresses: Noren L, Univ Uppsala, Dept Inorgan Chem, Angstrom Lab, Box 538, S-75121 Uppsala, Sweden. Univ Uppsala, Dept Inorgan Chem, Angstrom Lab, S-75121 Uppsala, Sweden. Stockholm Univ, Div Inorgan Chem, S-10691 Stockholm, Sweden. Stockholm Univ, DivAvailable from: 2006-11-08 Created: 2006-11-08 Last updated: 2011-01-14

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