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Uniform distribution of post-synthetic linker exchange in metal-organic frameworks revealed by Rutherford backscattering spectrometry
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström.
Uppsala University, Disciplinary Domain of Science and Technology, Physics, Department of Physics and Astronomy, Applied Nuclear Physics.
Uppsala University, Disciplinary Domain of Science and Technology, Physics, Department of Physics and Astronomy, Applied Nuclear Physics.ORCID iD: 0000-0002-5815-3742
Uppsala University, Disciplinary Domain of Science and Technology, Chemistry, Department of Chemistry - Ångström, Molecular Biomimetics.ORCID iD: 0000-0002-1691-729X
2017 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, Vol. 53, no 48, 6516-6519 p.Article in journal (Refereed) Published
Abstract [en]

Rutherford backscattering spectrometry (RBS) has been used for the first time to study post-synthetic linker exchange (PSE) in metal-organic frameworks. RBS is a non-invasive method to quantify the amount of introduced linker, as well as providing a means for depth profiling in order to identify the preferred localization of the introduced linker. The exchange of benzenedicarboxylate (bdc) by similarly sized 2-iodobenzenedicarboxylate (I-bdc) proceeds considerably slower than migration of I-dbc through the UiO-66 crystal. Consequently, the I-bdc is found evenly distributed throughout the UiO-66 samples, even at very short PSE exposure times.

Place, publisher, year, edition, pages
ROYAL SOC CHEMISTRY , 2017. Vol. 53, no 48, 6516-6519 p.
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:uu:diva-329662DOI: 10.1039/c7cc02631eISI: 000403211300032PubMedID: 28573305OAI: oai:DiVA.org:uu-329662DiVA: diva2:1142723
Funder
Swedish Research CouncilSwedish Energy AgencyEU, European Research Council, ERC-CoG2015-681895_MOFcatSwedish Foundation for Strategic Research , RIF-140053
Available from: 2017-09-20 Created: 2017-09-20 Last updated: 2017-09-20Bibliographically approved

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Paneta, ValentinaPrimetzhofer, DanielOtt, Sascha

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