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Structural, magnetic and hyperfine characterizations of nanocrystalline Zn-Cd doped nickel ferrites
Department of Electronics and Communication Engg., Birla Institute of Technology.
Uppsala University, Disciplinary Domain of Science and Technology, Technology, Department of Engineering Sciences, Solid State Physics.ORCID iD: 0000-0002-4561-9996
Department of Physics, National Institute of Technology Patna.
Department of Physics, National Institute of Technology Patna.
2017 (English)In: Journal of Magnetism and Magnetic Materials, ISSN 0304-8853, E-ISSN 1873-4766, Vol. 441, 710-717 p.Article in journal (Refereed) Published
Abstract [en]

In our present work, we have synthesized a series of Cd-Zn doped nickel ferrite ((Cd-0.5 Zn-x(x)) Ni0(.5)Fe(2)O(4); x = 0, 0.1, 0.2, 0.3, 0.4 and 0.5) through standard chemical co-precipitation method to study the influence of diamagnetic ions (Cd, Zn) on the magnetic properties of ferrites. XRD and Raman spectroscopy were employed for the structural characterizations. The refinement of the X-ray diffractogram data augmented by the Williamson-Hall plots showed the presence of Cd2+ vacancies and a strained crystal structure. The vibrational spectroscopy indicated the presence of lower space-group symmetry and a distorted crystal structure. Magnetic measurements showed the samples possessed low magnetic anisotropy along with a canted spin structure. The Mossbauer measurements confirmed the cation distribution and gave evidence of super transferred hyperfine interactions arising due to canted spin structure of the system.

Place, publisher, year, edition, pages
ELSEVIER SCIENCE BV , 2017. Vol. 441, 710-717 p.
Keyword [en]
Ferrite, Diamagnetic, Williamson-Hall plot, Raman spectroscopy, Mossbauer spectroscopy, Super transferred hyperfine interactions
National Category
Condensed Matter Physics Engineering and Technology
Identifiers
URN: urn:nbn:se:uu:diva-330522DOI: 10.1016/j.jmmm.2017.06.040ISI: 000408015500101OAI: oai:DiVA.org:uu-330522DiVA: diva2:1147881
Available from: 2017-10-09 Created: 2017-10-09 Last updated: 2017-10-11

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Nordblad, Per

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