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Synthesis, X-ray Diffraction Characterization, Mössbauer Spectroscopy, and Dielectric Properties of Solid Solutions in the PbFe2/3W1/3O3–PbSc2/3W1/3O3 System
Moscow Technol Univ, Moscow Inst Radio Engn Elect & Automat, Moscow, Russia.
Moscow Technol Univ, Moscow Inst Radio Engn Elect & Automat, Moscow, Russia.
Moscow Technol Univ, Moscow Inst Radio Engn Elect & Automat, Moscow, Russia.
Moscow Technol Univ, Moscow Inst Radio Engn Elect & Automat, Moscow, Russia.
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2018 (English)In: Inorganic Materials (Neorganicheskie materialy), ISSN 0020-1685, E-ISSN 1608-3172, Vol. 54, no 3, p. 288-294Article in journal (Refereed) Published
Abstract [en]

Ceramic Pb(Fe1–xSc x )2/3W1/3O3 samples with 0 ≤ x ≤ 1 have been prepared and characterized by X-ray diffraction, Mössbauer spectroscopy, and dielectric and pyroelectric measurements. The stoichiometry ranges of the perovskite solid solutions in this system have been identified, their structural parameters have been determined, and their dielectric permittivity, dielectric loss tangent, resistivity, and thermally stimulated depolarization current have been measured as functions of temperature. The composition dependences of the dielectric properties for the solid solutions have been obtained. The solid solutions have been shown to exhibit ferroelectric relaxor properties, with a well-defined maximum in their permittivity in the range 180–250 K.

Place, publisher, year, edition, pages
2018. Vol. 54, no 3, p. 288-294
Keywords [en]
ferroelectric ceramics, magnetoelectric materials, solid solutions, perovskite structure, dielectric properties, Mossbauer spectroscopy, X-ray powder diffraction
National Category
Condensed Matter Physics Engineering and Technology
Identifiers
URN: urn:nbn:se:uu:diva-351096DOI: 10.1134/S0020168518030056ISI: 000427490400013OAI: oai:DiVA.org:uu-351096DiVA, id: diva2:1208732
Available from: 2018-05-18 Created: 2018-05-18 Last updated: 2018-06-05Bibliographically approved

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Ivanov, SergeyShafeie, Samrand

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